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392219

Sigma-Aldrich

Cerium(III) nitrate hexahydrate

99.99% trace metals basis

Synonyme(s) :

Cerium trinitrate, Cerous nitrate hexahydrate, Nitric acid cerium salt

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About This Item

Formule linéaire :
Ce(NO3)3 · 6H2O
Numéro CAS:
10294-41-4
Poids moléculaire :
434.22
Numéro CE :
233-297-2
Numéro MDL:
MFCD00149631
Code UNSPSC :
12352302
ID de substance PubChem :
24864435
Nomenclature NACRES :
NA.23

Pureté

99.99% trace metals basis

Forme

crystals and lumps

Pertinence de la réaction

reagent type: catalyst
core: cerium

Impuretés

≤150.0 ppm Trace Rare Earth Analysis

Chaîne SMILES 

[Ce+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

Clé InChI

QQZMWMKOWKGPQY-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Cerium (III) nitrate hexahydrate is a white-to-yellowcrystalline salt, which is hygroscopic and air-sensitive. Cerium (III) nitratehexahydrate is highly soluble in water, alcohol, and acetone. Cerium (III)nitrate hexahydrate melts at 57 °C and begins to thermally decompose at190 °Cwith complete decomposition to the oxide by 400 °C.

Application

Cerium (III) nitrate hexahydrate is widely used as a sourceof cerium, especially in the synthesis of micro- or nano-structured ceria(cerium oxide). Researchers leverage the high solubility and low decompositiontemperature of cerium (III) nitrate hexahydrate in hydrothermal reactions,sol-gel processing, and co-precipitation/calcination reactions to synthesizeceria and cerium-compounds. For example, for one study materials scientistsprepared a two-dimensional cobalt-doped ceria nanosheet by co-precipitating andcalcining cerium nitrate and cobalt acetate. As another example, researchersused the high solubility of cerium nitrate to grow crystals of two-dimensionalrare-earth double perovskites. Researchers have also used cerium nitrate to formcomposites, such as graphene-ceria nanoparticle composites and TiO2/CeO2nanocomposites, utilizing cerium’s (III/IV) redox chemistry forlight-absorption and photocatalysis. One example, that shows the maturematerials engineering of cerium (III) nitrate chemistry, is a study that uses acalcium-doped cerium nanotube composite with lithiumbis(trifluoromethanesulfonyl)imide (LiTFSI) poly(ethylene oxide) for asolid-state lithium-ion electrolyte. The Ca-CeO2 nanotubes, which achievehigher concentrations of oxygen vacancies than undoped CeO2, were made byelectrospinning from a solution of cerium nitrate and calcium nitrate withpolyvinylpyrrolidone, which is removed by pyrolysis in a final calcination.

Pictogrammes

CorrosionEnvironment
GHS05,GHS09

Mention d'avertissement

Danger

Mentions de danger

H318,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Code de la classe de stockage

5.1B - Oxidizing hazardous materials

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
MKCB3831
MKBW1943V
MKBS4068V
MKBN9103V
MKBL8215V

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Shan Gao et al.
Small (Weinheim an der Bergstrasse, Germany), 16(19), e1906668-e1906668 (2020-04-17)
A high efficiency and great tunability of bandwidth and absorption-range electromagnetic wave absorber is proposed without precedent. A series of 2D carbon-based nanocomposites with the loading of cerium oxide (CN-Ce) and other types of rare earth oxides (CN-REOs) can be
Chao Shi et al.
Journal of the American Chemical Society, 142(1), 545-551 (2019-12-12)
As a major branch of hybrid perovskites, two-dimensional (2D) hybrid double perovskites are expected to be ideal systems for exploring novel ferroelectric properties, because they can accommodate a variety of organic cations and allow diverse combinations of different metal elements.
Pratik P Dholabhai et al.
Physical chemistry chemical physics : PCCP, 17(23), 15375-15385 (2015-05-23)
Grain boundaries (GBs) dictate vital properties of nanocrystalline doped ceria. Thus, to understand and predict its properties, knowledge of the interaction between dopant-defect complexes and GBs is crucial. Here, we report atomistic simulations, corroborated with first principles calculations, elucidating the
Martha Cobo et al.
Journal of environmental management, 158, 1-10 (2015-05-02)
The catalytic hydrodechlorination (HDC) of high concentrations of trichloroethylene (TCE) (4.9 mol%, 11.6 vol%) was studied over 1%Pd, 1%Rh and 0.5%Pd-0.5%Rh catalysts supported on CeO2 under conditions of room temperature and pressure. For this, a one-phase system of NaOH/2-propanol/methanol/water was designed
Ana Silva-Dias et al.
The Journal of antimicrobial chemotherapy, 70(4), 1083-1093 (2015-01-06)
The objective of this study was to clarify the antifungal properties of cerium, a lanthanide member, against Candida species. A comprehensive study with planktonic and sessile cells was performed. The ability of cerium nitrate (CN) to impair in vitro and
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