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267317

Sigma-Aldrich

Rhenium

foil, thickness 0.25 mm, 99.98% trace metals basis

Synonyme(s) :

Rhenium element

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About This Item

Formule empirique (notation de Hill):
Re
Numéro CAS:
Poids moléculaire :
186.21
Numéro MDL:
Code UNSPSC :
12141737
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Pureté

99.98% trace metals basis

Forme

foil

Description

19.3 μΩ-cm, 20°C

Épaisseur

0.25 mm

Point d'ébullition

5596 °C (lit.)
5627 °C (lit.)

Pf

3180 °C (lit.)

Densité

21.02 g/cm3 (lit.)

Chaîne SMILES 

[ReH]

InChI

1S/Re

Clé InChI

WUAPFZMCVAUBPE-UHFFFAOYSA-N

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Description générale

Rhenium is a very hard, corrosion, and wear-resistant rare metal with ahigh atomic number. It is widely used in the field of catalysis and the preparationof alloys for jet engines.

Application

Rhenium can be used as a working electrode for electrochemical hydrogen evolution reactions.

It can be used as an additive to prepare a molybdenum-titanium-zirconium (TZM) alloy joint to improve its tensile strength.

It can also be used as a catalyst for various hydrodeoxygenation reactions.

Quantité

3.3 g = 25 × 25 mm; 13.2 g = 50 × 50 mm

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

nwg

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Titel Jurca et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4278-4286 (2013-02-02)
The development of rhenium(I) chemistry has been restricted by the limited structural and electronic variability of the common pseudo-octahedral products fac-[ReX(CO)3L2] (L2 = α-diimine). We address this constraint by first preparing the bidentate bis(imino)pyridine complexes [(2,6-{2,6-Me2C6H3N=CPh}2C5H3N)Re(CO)3X] (X = Cl 2
Ties J Korstanje et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(39), 13224-13234 (2013-08-16)
Rhenium-based complexes are powerful catalysts for the dehydration of various alcohols to the corresponding olefins. Here, we report on both experimental and theoretical (DFT) studies into the mechanism of the rhenium-catalyzed dehydration of alcohols to olefins in general, and the
Raphael Horvath et al.
Inorganic chemistry, 52(3), 1304-1317 (2013-01-15)
Transition-metal complexes of the types [Re(CO)(3)Cl(NN)], [Re(CO)(3)py(NN)](+), and [Cu(PPh(3))(2)(NN)](+), where NN = 4,4'-bis(5-phenyl-1,3,4-oxadiazol-2-yl)-2,2'-bipyridine (OX) and 4,4'-bis(N,N-diphenyl-4-[ethen-1-yl]-aniline)-2,2'-bipyridine (DPA), have been synthesized and characterized. Crystal structures for [Re(CO)(3)Cl(DPA)] and [Cu(PPh(3))(2)(OX)]BF(4) are presented. The crystal structure of the rhenium complex shows a trans
Jonathan M Smieja et al.
Inorganic chemistry, 52(5), 2484-2491 (2013-02-20)
Electrocatalytic properties, X-ray crystallographic studies, and infrared spectroelectrochemistry (IR-SEC) of Mn(bpy-tBu)(CO)3Br and [Mn(bpy-tBu)(CO)3(MeCN)](OTf) are reported. Addition of Brönsted acids to CO2-saturated solutions of these Mn complexes and subsequent reduction of the complexes lead to the stable and efficient production of
Wilber Quispe-Tintaya et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(21), 8668-8673 (2013-04-24)
No significant improvement in therapy of pancreatic cancer has been reported over the last 25 y, underscoring the urgent need for new alternative therapies. Here, we coupled a radioisotope, (188)Rhenium, to an attenuated (at) live Listeria monocytogenes (Listeria(at)) using Listeria-binding

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