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262587

Sigma-Aldrich

Chloroplatinic acid solution

8 wt. % in H2O

Synonyme(s) :

Hexachloroplatinic acid solution, Hydrogen hexachloroplatinate(IV) solution, Platinic chloride solution, Platinum(IV) chloride solution

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About This Item

Formule linéaire :
H2PtCl6
Numéro CAS:
16941-12-1
Poids moléculaire :
409.81
Numéro MDL:
MFCD00011330
Code UNSPSC :
12161600
ID de substance PubChem :
24855878
Nomenclature NACRES :
NA.22

Forme

liquid

Niveau de qualité

100

Pertinence de la réaction

core: platinum
reagent type: catalyst

Concentration

8 wt. % in H2O

Densité

1.05 g/mL at 25 °C

Chaîne SMILES 

Cl.Cl.Cl[Pt](Cl)(Cl)Cl

InChI

1S/6ClH.Pt/h6*1H;/q;;;;;;+4/p-4

Clé InChI

GBFHNZZOZWQQPA-UHFFFAOYSA-J

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Description générale

Chloroplatinicacid (H2PtCl6) is a hygroscopic inorganic compound that is widely used as a catalyst for hydrosilylation, hydrogenation, carbonylation, oxidation and coupling reactions.

Chloroplatinic acid solution catalyses the hydrosilylation reaction of 1-Hexyne to form l,6-Bis(trichlorosilyl)hexane.

Application

Chloroplatinic acid solution used as:
  • Platinum precursor in the synthesis of platinum nanoparticles using hydrazine as a reducing agent.
  • An electrolyte in the preparation of various carbon-supported platinum nanomaterials with H2SO4 by electrodeposition method in the presence or absence of organic additives.
  • An anionic precursor in the preparation of Pt/SBA_BEA catalyst for the hydro isomerization of n-hexadecane.
  • A Pt precursor in the preparation of PVP-protected Pt-nanoparticles by seed-mediated growth method.

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2

Organes cibles

Kidney

Code de la classe de stockage

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Klas Tybrandt et al.
Advanced materials (Deerfield Beach, Fla.), 30(15), e1706520-e1706520 (2018-03-01)
Electrical interfacing with neural tissue is key to advancing diagnosis and therapies for neurological disorders, as well as providing detailed information about neural signals. A challenge for creating long-term stable interfaces between electronics and neural tissue is the huge mechanical
Composite of Pt/AlSBA-15+ zeolite catalyst for the hydroisomerization of n-hexadecane: The effect of platinum precursor
Fedyna M, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 305, 110366-110366 (2020)
B X E Desbiolles et al.
Nano letters, 20(6), 4520-4529 (2020-05-20)
Atomic force microscopy based approaches have led to remarkable advances in the field of mechanobiology. However, linking the mechanical cues to biological responses requires complementary techniques capable of recording these physiological characteristics. In this study, we present an instrument for
B R Nechay et al.
Cancer treatment reports, 68(9), 1135-1141 (1984-09-01)
Cisplatin and chloroplatinic acid were examined for in vitro inhibition of human renal microsomal adenosine triphosphatases activated by Na+ + K+ + Mg2+, Mg2+, and Ca2+. The concentrations of cisplatin to inhibit 50% of activity (I50) were approximately 7 X
Shiori Hanada et al.
Journal of the American Chemical Society, 131(41), 15032-15040 (2009-09-30)
The synergetic effect of two Si-H groups leads to efficient reduction of carboxamides to amines by platinum catalysts under mild conditions. The rate of the reaction is dependent on the distance of two Si-H groups; 1,1,3,3-tetramethyldisiloxane (TMDS) and 1,2-bis(dimethylsilyl)benzene are
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