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545856

Sigma-Aldrich

Lithium hydroxide

powder, reagent grade, ≥98%

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About This Item

Linear Formula:
LiOH
CAS Number:
1310-65-2
Molecular Weight:
23.95
EC Number:
215-183-4
MDL number:
MFCD00011095
UNSPSC Code:
12352106
PubChem Substance ID:
329758039
NACRES:
NA.21

grade

reagent grade

Assay

≥98%

form

powder

mp

470 °C (dec.) (lit.)

solubility

water: soluble 71 g/L at 20 °C

SMILES string

[Li+].[OH-]

InChI

1S/Li.H2O/h;1H2/q+1;/p-1

InChI key

WMFOQBRAJBCJND-UHFFFAOYSA-M

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General description

Lithium hydroxide (LiOH) is an alkali metal hydroxide. Lithium chloride solution in water on electrolysis forms LiOH. In respiratory apparatus and submarines, it is utilized to uptake carbon dioxide. A study on the redox mechanism of titanium dioxide (TiO2) using cyclic voltammetry, X-ray diffraction, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) in aqueous LiOH electrolyte has been reported.

Application

Lithium hydroxide has been used in the following processes:
  • Synthesis of lithium-doped zinc oxide (ZnO) thin films.
  • Preparation of lithium glyceroxide/hydroxide catalysts by reacting with glycerol.
  • As a catalyst to generate unsaturated ketones via Michael addition of β-dicarbonyl compounds.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Lithium Hydroxide-Catalyzed Conjugate Addition of β-Dicarbonyl Compounds.
Bonadies F, et al.
ChemInform, 26(23) (1995)
G F Zhang et al.
Journal of animal science, 92(7), 2987-2995 (2014-05-08)
The objective of this experiment was to determine the net energy requirements for maintenance of growing and finishing pigs using regression models. Thirty-six growing (27.38 ± 2.24 kg) and 36 finishing (70.25 ± 2.61 kg) barrows were used and within
Eagleson M.
Concise Encyclopedia Chemistry, 605-605 (1994)
Low-Temperature, Solution-Processed and Alkali Metal Doped ZnO for High-Performance Thin-Film Transistors.
Park SY, et al.
Advanced Mat., 24(6), 834-838 (2012)
Electrochemical behavior of anatase TiO2 in aqueous lithium hydroxide electrolyte.
Manickam M, et al.
J. Appl. Electrochem., 36(5), 599-602 (2006)
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