92337

Bromotrimethylsilane

purum, ≥97.0% (AT)

• Synonym(s): TMBS, Trimethylbromosilane, Trimethylsilyl bromide
• Linear Formula: (CH₃)₃SiBr
• CAS Number: 2857-97-8
• Molecular Weight: 153.09
• Beilstein: 1731135
• EC Number: 220-672-0
• MDL number: MFCD00000048
• UNSPSC Code: 12352101
• PubChem Substance ID: 329769891
• NACRES: NA.22

Properties

• grade: purum
• Quality Level: 200
• Assay: ≥97.0% (AT)
• form: liquid
• contains: silver wool as stabilizer
• refractive index: n20/D 1.424 (lit.); n20/D 1.424
• bp: 79 °C (lit.)
• density: 1.16 g/mL at 25 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: C[Si](C)(C)Br
• InChI: 1S/C3H9BrSi/c1-5(2,3)4/h1-3H3
• InChI key: IYYIVELXUANFED-UHFFFAOYSA-N

Description

General description

Bromotrimethylsilane is used with Cl₃ to catalyze the direct allylation of a variety of alcohols with allyltrimethylsilane.

Application

Bromotrimethylsilane may be used as a derivatizing reagent for the determination of alkyl lysophospholipids in cell culture media using gas chromatography technique.

Other Notes

Powerful silylating agent ; Cleavage of ethers ; Smooth cleavage of phosphonic and phosphoric alkyl esters

Safety Information

• Pictograms: GHS02,GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H225 - H314 - H335 - H410
• Precautionary Statements: P210 - P233 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 10.4 °F - closed cup
• Flash Point(C): -12 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves