ALD00004

Li-Yu t-Butyl Quinoline

95%

• Synonym(s): 3,4-Dihydro-7-tert-butyl-2,5-dimethyl-2H-pyrano[2,3-b]quinoline
• Empirical Formula (Hill Notation): C₁₈H₂₃NO
• Molecular Weight: 269.38
• MDL number: MFCD28016344
• UNSPSC Code: 12352005
• PubChem Substance ID: 329772510
• NACRES: NA.22

Properties

• Assay: 95%
• form: solid
• reaction suitability: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• mp: 202-207 °C
• SMILES string: CC1=C2C(OC(C)CC2)=NC3=C1C=C(C(C)(C)C)C=C3
• InChI: 1S/C18H23NO/c1-11-6-8-14-12(2)15-10-13(18(3,4)5)7-9-16(15)19-17(14)20-11/h7,9-11H,6,8H2,1-5H3
• InChI key: HGKGTNXPFXRVQB-UHFFFAOYSA-N

Description

Application

Ligand is optimal for gamma C-H functionalization of aliphatic acids through Pd-catalyzed C-H activation. The Yu group has demonstrated a variety of transformations, such as olefination, carbonylation, and arylation.

Other Notes

Ligand-Enabled g-C–H Olefination and Carbonylation: Construction of b-Quaternary Carbon Centers

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable