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A32608

Sigma-Aldrich

Allyl glycidyl ether

≥99%

Synonym(s):

1-Allyloxy-2,3-epoxypropane, Allyl 2,3-epoxypropyl ether

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About This Item

Empirical Formula (Hill Notation):
C6H10O2
CAS Number:
106-92-3
Molecular Weight:
114.14
Beilstein:
105871
EC Number:
203-442-4
MDL number:
MFCD00005143
UNSPSC Code:
12162002
PubChem Substance ID:
24890754
NACRES:
NA.23

vapor density

3.9 (vs air)

Quality Level

200

vapor pressure

4.7 mmHg ( 25 °C)

Assay

≥99%

form

liquid

refractive index

n20/D 1.433 (lit.)

bp

154 °C (lit.)

density

0.962 g/mL at 25 °C (lit.)

SMILES string

C=CCOCC1OC1

InChI

1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2

InChI key

LSWYGACWGAICNM-UHFFFAOYSA-N

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General description

Allyl glycidyl ether (AGE) is a monomer that acts as a building block in the polymerization of poly(allyl glycidyl ether) by anionic ring opening mechanism. It is industrially prepared by the reacting allyl alcohol and epichlorohydrin.

Application

AGE can be used as a terminal epoxy group in the development of adhesive surfaces by hydrosilylation process. It can also be used in the synthesis of polymeric electrolytes for the fabrication of lithium batteries.
Useful in hydrosilylation, including the H2PtCl6·xH2O (cat. no. 206083) catalyzed hydrosilylation of siloxanes to epoxysiloxanes.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

134.6 °F - closed cup

Flash Point(C)

57 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Fatima M Plieva et al.
Journal of separation science, 27(10-11), 828-836 (2004-09-10)
Supermacroporous monolithic polyacrylamide (pAAm)-based columns have been prepared by radical cryo-copolymerization (copolymerization in the moderately frozen system) of acrylamide with functional co-monomer, allyl glycidyl ether (AGE), and cross-linker N,N'-methylene-bis-acrylamide (MBAAm) directly in glass columns (ID 10 mm). The monolithic columns
Macromolecules, 27, 3397-3397 (1994)
Qin Zeng et al.
International journal of nanomedicine, 7, 985-997 (2012-03-14)
The generation of anti-adenovirus neutralizing antibody (NAb) in humans severely restricts the utilization of recombinant adenovirus serotype 5 (Ad5) vectors in gene therapy for a wide range of clinical trials. To overcome this limitation, we ionically complexed Ad5 with a
Cancan Li et al.
Langmuir : the ACS journal of surfaces and colloids, 27(17), 11174-11179 (2011-08-02)
Poly(allyl glycidyl ether) (PAGE) and poly(ethylene glycol) (PEG) blocks were sequentially grown via anionic polymerization to form four block copolymer arms on a cholic acid (CA) core, yielding star block copolymers (CA(AGE(8)-b-EG(n))(4)) with low polydispersities (ca. 1.05). The introduction of
M Chiari et al.
Electrophoresis, 21(8), 1521-1526 (2000-06-01)
A fully automated coating procedure was devised based on adsorption of a new polymer, poly(dimethylacrylamide-co-allyl glycidyl ether) onto the capillary surface. The whole procedure takes less than 30 min and does not require the use of organic solvents, viscous solutions
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