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Key Documents

774251

Sigma-Aldrich

Ethylene sulfite

greener alternative

≥99.0%

Synonym(s):

1,3,2-Dioxathiolan-2-oxide, Cyclic ethylene sulfite, ES, Glycol sulfite

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About This Item

Empirical Formula (Hill Notation):
C2H4O3S
CAS Number:
Molecular Weight:
108.12
Beilstein:
1237109
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

Assay

≥99.0%

form

liquid

greener alternative product characteristics

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Learn more about the Principles of Green Chemistry.

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refractive index

n20/D 1.445 (lit.)
n20/D 1.447

bp

159.1 °C (lit.)

density

1.426 g/mL at 25 °C (lit.)
1.433 g/mL at 25 °C

application(s)

battery manufacturing

greener alternative category

SMILES string

O=S1OCCO1

InChI

1S/C2H4O3S/c3-6-4-1-2-5-6/h1-2H2

InChI key

WDXYVJKNSMILOQ-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Ethylene sulfite (ES) is a sulfur analog of ethylene carbonate (EC), which can be used as an electrolytic additive for the formation of liquid electrolytes. These electrolytes are useful in the fabrication of lithium-ion batteries.
Ethylene sulfite is used as a film forming and high temperature additive for electrolytes in lithium ion batteries. It improves decomposition resistance of electrolyte.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

197.1 °F

Flash Point(C)

91.7 °C


Certificates of Analysis (COA)

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Ethylene Sulfite as Electrolyte Additive for Lithium-Ion Cells with Graphitic Anodes
Wrodnigg GH, et al.
Journal of the Electrochemical Society, 146(2), 470-472 (1999)
The reductive mechanism of ethylene sulfite as solid electrolyte interphase film-forming additive for lithium ion battery
Xing L, et al.
Journal of Power Sources, 196(16), 7044-7047 (2011)
Joseph P O'Shea et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 96, 207-216 (2015-07-29)
Novel formulations that overcome the solubility limitations of poorly water soluble drugs (PWSD) are becoming ever more critical to a drug development process inundated with these compounds. There is a clear need for developing bio-enabling formulation approaches to improve oral
Dharmendra K Yadav et al.
AAPS PharmSciTech, 16(4), 855-864 (2015-01-15)
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Hywel D Williams et al.
Journal of pharmaceutical sciences, 103(6), 1734-1746 (2014-04-18)
The current study determined the extent to which the desorption of lipid-based formulations (LBFs) from a mesoporous magnesium aluminometasilicate (Neusilin®-US2) carrier is governed by drug properties, LBF composition, and LBF-to-adsorbent ratio. A secondary objective was to evaluate the impact of

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