902896
Black phosphorus
>=20 micro gram/ml in NMP
Synonym(s):
2D Black phosphorus, Phosphorene
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About This Item
Linear Formula:
P
UNSPSC Code:
12161600
NACRES:
NA.23
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form
liquid
General description
Black phosphorus, also known as phosphorene, is a stable allotrope of phosphorus with semiconducting properties. It has a good mechanical property and a tunable band structure. BP also has good anisotropic thermal, electrical and optical properties.
Application
BP is a two dimensional (2D) p-type material, which shows high hole mobility up to 1000 cm2V-1s-1. It can be used in the fabrication of energy storage devices such as lithium-ion batteries. BP can also be used in a variety of biomedical applications such as photodynamic therapy.
Owing to the unique properties such as thickness dependent tunable band gap, strong in-plane anisotropy, and high carrier mobility, 2D-black phosphorous has attracted significant attention recently. The applications of 2D-black phosphorous extend from electronics, to optoelectronics, spintronics, thermoelectrics and storage devices.
Caution
Material is very oxygen sensitive. Please handle under inert atmosphere.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
Flash Point(F)
195.8 °F - closed cup
Flash Point(C)
91 °C - closed cup
Certificates of Analysis (COA)
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Production of few-layer phosphorene by liquid exfoliation of black phosphorus.
Brent, et al.
Chemical Communications (Cambridge, England), 50, 13338-13341 (2014)
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices.
Pang J, et al.
Advanced Energy Materials, 8, 1702093-1702093 (2018)
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility.
Liu H, et al.
ACS Nano, 8, 4033-4041 (2014)
Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy.
Woomer, et al.
ACS Nano, 9, 8869-8884 (2015)
Recent advances in synthesis, properties, and applications of phosphorene.
Akhtar M, et al.
NPJ 2D materials and applications, 5, 1-1 (2017)
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