Skip to Content
Merck
All Photos(2)

Key Documents

View All Documentation

668001

Sigma-Aldrich

Silver bis(trifluoromethanesulfonyl)imide

97%

Synonym(s):

Silver bis(trifluoromethanesulfonyl)amide, Silver bis(trifluoromethylsulfonyl)amide, Silver triflimide

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C2AgF6NO4S2
CAS Number:
189114-61-2
Molecular Weight:
388.01
MDL number:
MFCD08457644
UNSPSC Code:
12161600
PubChem Substance ID:
24884953
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

core: silver
reagent type: catalyst

mp

248.8 °C

SMILES string

FC(F)(F)S(=O)(=O)N([Ag])S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Ag/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key

HSYLTRBDKXZSGS-UHFFFAOYSA-N

General description

Silver bis(trifluoromethanesulfonyl)imide is a silver-based salt that is widely used as a catalyst in organic synthesis. It is used in the C3 regioselective alkylation of indole derivatives via conjugated addition type reactions with α, β-enones. It is also used as a p-type dopant for efficient and stable solid-state dye-sensitized and perovskite solar cells.

Application

Gold Catalysts — 21st Century ′Gold Rush′

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCQ9048
MKCQ6171
MKCP6527
MKCK7297
MKCJ3271

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

Gold Catalyst

We are proud to offer a treasure-trove of gold precatalysts and silver salts, as well as an extensive portfolio of unsaturated building blocks to accelerate your research success in this exciting field.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service