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260916

Sigma-Aldrich

Ethylenebis(triphenylphosphine)platinum(0)

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About This Item

Linear Formula:
[(C6H5)3P]2Pt(H2C=CH2)
CAS Number:
12120-15-9
Molecular Weight:
747.70
MDL number:
MFCD00012028
UNSPSC Code:
12161600
PubChem Substance ID:
24855778
NACRES:
NA.22

reaction suitability

core: platinum
reagent type: catalyst

mp

129-132 °C (dec.) (lit.)

SMILES string

[Pt].C=C.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.C2H4.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h2*1-15H;1-2H2;

InChI key

RZUASTIKPBCXPU-UHFFFAOYSA-N

Application

Nucleophilic metal species for ligand exchangewith alkenes and alkynes; catalysts for hydrosilation; reagent for oxidative addition to activated C-X bonds

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Gevorgyan, V.; Borisova, L. et al.
Journal of Organometallic Chemistry, 424, 15-15 (1992)
Kurosawa, H.; Ogoshi, S. et al.
Journal of the American Chemical Society, 112, 2813-2813 (1990)
Uchimaru,Y.; Brandl, P.; Tanaka, M.; Goto, M.
Journal of the Chemical Society. Chemical Communications, 744-744 (1993)

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