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vapor pressure
14.46 psi ( 55 °C)
3.67 psi ( 20 °C)
Quality Level
Assay
99%
form
liquid
refractive index
n20/D 1.423 (lit.)
bp
54-55 °C (lit.)
density
0.927 g/mL at 25 °C (lit.)
functional group
ether
storage temp.
2-8°C
SMILES string
C1CC=CO1
InChI
1S/C4H6O/c1-2-4-5-3-1/h1,3H,2,4H2
InChI key
JKTCBAGSMQIFNL-UHFFFAOYSA-N
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General description
The enantioselective Heck arylation of 2,3-dihydrofuran with aryl iodides was studied.
Application
2,3-Dihydrofuran is a versatile reagent used in lanthanide-catalyzed Diels-Alder reactions with 2-pyrones and in Rh(II)-stabilized cycloadditions with vinylcarbenoids.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-11.2 °F - closed cup
Flash Point(C)
-24 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 5(1), 51-55 (2006-01-06)
The bicyclic oxetanes and resulting from photocycloaddition of aromatic aldehydes to 2,3-dihydrofuran, were efficiently cleaved by means of electron-transfer reduction, photoinduced by the electronically excited reductants 1-methoxynaphthalene (MN) and 2,7-dimethoxynaphthalene (DMN) in acetonitrile. The fluorescence quenching rates of DMN/MN by
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