940356

GPhos Pd G3 ChemBeads

• Sinónimos: Methanesulfonato[Dicyclohexyl[3-(1,1-dimethylethoxy)-6-methoxy-2′,6′-bis(1-methylethyl)[1,1′-biphenyl]-2-yl]phosphine](2′-amino-1,1′-biphenyl-2-yl)palladium(II) ChemBeads
• Fórmula empírica (notación de Hill): C₄₈H₆₆NO₅PPdS
• Número de CAS: 2489525-82-6
• Peso molecular: 906.50
• Código UNSPSC: 12352100

Propiedades

• formulario: solid
• Nivel de calidad: 100
• composición: , 4-6 wt. % (loading)
• idoneidad de la reacción: reagent type: catalyst
• cadena SMILES: O=S(O[Pd]([P](C1CCCCC1)(C2CCCCC2)C3=C(C4=C(C(C)C)C=CC=C4C(C)C)C(OC)=CC=C3OC(C)(C)C)C5=C(C6=C(N)C=CC=C6)C=CC=C5)(C)=O
• InChI: InChI=1S/C35H53O2P.C12H10N.CH4O3S.Pd/c1-24(2)28-20-15-21-29(25(3)4)32(28)33-30(36-8)22-23-31(37-35(5,6)7)34(33)38(26-16-11-9-12-17-26)27-18-13-10-14-19-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15,20-27H,9-14,16-19H2,1-8H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
• Clave InChI: PLMOFCQYSAAMKA-UHFFFAOYSA-M

Descripción

Descripción general

The ChemBeads product of the GPhos ligand combined with the Buchwald third Generation Palladacycle. The GPhos motif gives superb activity while having greater stability relative to other superbulky Buchwald ligands. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE). GPhos Pd G3 has been used in: - The production of chiral N-arylamines via a telescoped transaminase-Buchwald-Hartwig Amination cascade.

Aplicación

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical. For general uses, product is also available in powdered form (920460 )

Características y beneficios

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3