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Merck

34115

Supelco

BDE No 77 solution

50 μg/mL in isooctane, analytical standard

Sinónimos:

3,3′,4,4′-Tetrabromodiphenyl ether solution, 3,3′,4,4′-TetraBDE, PBDE 77

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About This Item

Fórmula empírica (notación de Hill):
C12H6Br4O
Número de CAS:
Peso molecular:
485.79
Número CE:
Número MDL:
Código UNSPSC:
41116107
ID de la sustancia en PubChem:
NACRES:
NA.24

grado

analytical standard

caducidad

limited shelf life, expiry date on the label

concentración

50 μg/mL in isooctane

técnicas

HPLC: suitable
gas chromatography (GC): suitable

aplicaciones

environmental

formato

single component solution

temp. de almacenamiento

2-8°C

cadena SMILES

Brc1ccc(Oc2ccc(Br)c(Br)c2)cc1Br

InChI

1S/C12H6Br4O/c13-9-3-1-7(5-11(9)15)17-8-2-4-10(14)12(16)6-8/h1-6H

Clave InChI

RYGLOWMCGZHYRQ-UHFFFAOYSA-N

Categorías relacionadas

Descripción general

BDE No 77 is a contaminant found to be persistent in the environment with very low acute toxicity. It belongs to the class of polybrominated diphenyl ethers. It can find wide applications as additive flame-retardants in consumer products ranging from textiles to polymers.

Aplicación

BDE No 77 may be used as an analytical reference standard to determine analyte present in river sediments using gas chromatography coupled to mass spectrometry (GC-MS) and selective pressurized liquid extraction followed by gas chromatography coupled to negative ion chemical ionization-mass spectrometry (GC-NCI-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Otras notas

The customer needs to make sure that the standard is homogeneous, this can be achieved by shaking, vortexing , or sonicating the ampoule before opening the ampoule. Care should be taken when opening the ampoule to avoid any injuries from the broken glass.
The standard should be transferred to a clean and appropriate vial or flask using clean pipettes or micro pipettes. The vial should be immediately capped to avoid any loss or evaporation of the solvent.
After opening the ampoule, the standard should not be stored or kept in the ampoule. To preserve the integrity of the product, the standard should be transferred to an appropriate vial that must be capped and stored according to the recommendation on the Certificate of Analysis.

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Central nervous system

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

10.4 °F - closed cup

Punto de inflamabilidad (°C)

-12 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Visite la Librería de documentos

Determination of decabromodiphenyl ether in sediments using selective pressurized liquid extraction followed by GC-NCI-MS.
Eljarrat E, et al.
Analytical and Bioanalytical Chemistry, 378(3), 610-614 (2004)
GC / MS analysis of polybrominated diphenyl ethers in fish collected from the Inland Sea of ??Seto, Japan.
Akutsu K, et al.
Chemosphere, 44(6), 1325-1333 (2001)
Karim Zuhra et al.
Cells, 8(8) (2019-08-07)
Hydrogen sulfide (H2S) is an endogenously produced signaling molecule. The enzymes 3-mercaptopyruvate sulfurtransferase (MST), partly localized in mitochondria, and the inner mitochondrial membrane-associated sulfide:quinone oxidoreductase (SQR), besides being respectively involved in the synthesis and catabolism of H2S, generate sulfane sulfur

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