MX1123

1-Methylimidazole

• Sinónimos: 1-Methylimidazole, N-Methylimidazole, dna
• Fórmula lineal: CH₃-NCH=NCH=CH-
• Número de CAS: 616-47-7
• Número MDL: MFCD00005292
• Código UNSPSC: 12352100
• Número índice de la CE: 210-484-7

Propiedades

• presión de vapor: 0.4 hPa ( 20 °C)
• Nivel de calidad: 200
• formulario: liquid
• pH: 9.5-10.5 (20 °C, 50 g/L in H₂O)
• bp: 198 °C/1013 hPa
• mp: -2 °C
• temperatura de transición: flash point 92 °C
• Condiciones de envío: ambient
• temp. de almacenamiento: room temp
• InChI: 1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3
• Clave InChI: MCTWTZJPVLRJOU-UHFFFAOYSA-N

Descripción

Aplicación

1-Methylimidazole can be used as an organocatalyst to synthesize:

• 4-amino-3,5-dicyano-6-arylphthalates via one-pot, a three-component reaction between arylidenemalononitriles, dialkyl ­acetylenedicarboxylates, and malononitrile.
• Aromatic and aliphatic carbamates from hydroxamic acids via the Lossen rearrangement.
• Tetrahydrobenzo[b]pyrans via three-component cyclocondensation reaction between aromatic aldehydes, malononitrile, and dimedone.

It can also be used as:

• A co-catalyst in copper-catalyzed, greener oxidation of alcohols to carbonyl compounds under aerobic conditions.
• A solvent/complexing agent in the preparation of CuInS₂ n-type semiconductive particles.
• A co-additive in the synthesis of acid-sensitive epoxides by methyltrioxorhenium-catalyzed epoxidation of alkenes with H₂O₂.

Nota de análisis

Assay (GC)99.0% minDensity at 20°C1.03-1.04g/mLFormClear, liquidWater (H2O)150ppm max

Información de seguridad

• Pictogramas: GHS06,GHS08,GHS05
• Palabra de señalización: Danger
• Frases de peligro: H302,H311,H314,H361d
• Consejos de prudencia: P202 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Clasificaciones de peligro: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B
• Código de clase de almacenamiento: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Clase de riesgo para el agua (WGK): WGK 2
• Punto de inflamabilidad (°F): 197.6 °F - closed cup
• Punto de inflamabilidad (°C): 92 °C - closed cup