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924350

Tris(1-adamantyl)phosphine

Umicore

Sinónimos:

P(Ad)3

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About This Item

Nivel de calidad

Formulario

powder

idoneidad de la reacción

reagent type: ligand

grupo funcional

phosphine

Aplicación

Tris(1-adamantyl)phosphine, P(Ad)3, is a crystalline solid phosphine ligand that exhibits electron releasing character greater than most alkylphosphines. This ligand had demonstrated uses in many cross-coupling reactions, including the Suzuki-Miyaura coupling.

Almacenamiento y estabilidad

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Información legal

Product of Umicore

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

Additional information available at www.pmc.umicore.com

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Tri(1-adamantyl)phosphine: Expanding the Boundary of Electron-Releasing Character Available to Organophosphorus Compounds
Liye Chen, Peng Ren, and Brad P. Carrow
Journal of the American Chemical Society, Volume 138, Issue 20, 6392-6395 (2016)

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