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Merck

759546

Sigma-Aldrich

Lithium iron(II) phosphate

greener alternative

powder, <5 μm particle size (BET), >97% (XRF)

Sinónimos:

Ferrous lithium phosphate, Iron lithium phosphate, LFP, Triphylite

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About This Item

Fórmula lineal:
LiFePO4
Número de CAS:
Peso molecular:
157.76
Número MDL:
Código UNSPSC:
26111700
NACRES:
NA.23

grado

battery grade

Nivel de calidad

Ensayo

>97% (XRF)

Formulario

powder

mol peso

Mw 157.76 g/mol

composición

LiFePO4

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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tamaño de partícula

<5 μm (BET)

mp

>300 °C (lit.)

densidad

3.6 g/cm3 (lit.)

aplicaciones

battery manufacturing

categoría alternativa más sostenible

cadena SMILES

[Fe+2].[Li+].[P](=O)([O-])([O-])[O-]

InChI

1S/Fe.Li.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q+2;+1;/p-3

Clave InChI

GELKBWJHTRAYNV-UHFFFAOYSA-K

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Descripción general

Lithium iron(II) phosphate (LiFePO4), also called LFP, is a crystalline, grey-to-black powder with an olivine crystal structure. This unique structure facilitates efficient diffusion of lithium-ions, thanks to the three-dimensional interconnected iron phosphate tetrahedra that form pathways for lithium ions to diffuse. Additionally, the structure is highly stable, not deforming, even after thousands of cycles of lithium intercalation. Our LiFePO4 powder is manufactured to meet high purity with a tightly controlled particle size of less than 5 μm.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.

Aplicación

LiFePO4 is a widely used cathode for rechargeable Li batteries. It has high energy density, wide operating temperature, thermal stability, long cycle life and application life, environmental friendliness, and safety that make it a promising electrode material for greener and safer lithium-ion batteries.

Características y beneficios

LiFePO4-based batteries can last longer, operate safely and reliably, and power devices in a wide range of temperatures.
✔ Achieves 1000s of cycles
✔ Safer than cobalt or manganese-based cathode materials
✔ Reliable performance

Información legal

Product of Engi-Mat Co.

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Visite la Librería de documentos

P Subramanya Herle et al.
Nature materials, 3(3), 147-152 (2004-03-03)
The provision of efficient electron and ion transport is a critical issue in an exciting new group of materials based on lithium metal phosphates that are important as cathodes for lithium-ion batteries. Much interest centres on olivine-type LiFePO(4), the most
Kim, G. T.; et al.
Journal of Power Sources, 196, 2187-2187 (2011)
Low temperature hydrothermal synthesis of battery grade lithium iron phosphate
Benedek P, et al.
Royal Society of Chemistry Advances, 7(29), 17763-17767 (2017)
Byoungwoo Kang et al.
Nature, 458(7235), 190-193 (2009-03-13)
The storage of electrical energy at high charge and discharge rate is an important technology in today's society, and can enable hybrid and plug-in hybrid electric vehicles and provide back-up for wind and solar energy. It is typically believed that

Artículos

Professor Qiao’s laboratory lays out recent advances in conversion type lithium metal fluoride batteries. This review explores key concepts in developing electrochemically stable microstructures for wide Li-ion insertion channels.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Lithium-ion batteries (LIBs) have been widely adopted as the most promising portable energy source in electronic devices because of their high working voltage, high energy density, and good cyclic performance.

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