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710733

Sigma-Aldrich

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

Sinónimos:

1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide

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About This Item

Fórmula empírica (notación de Hill):
C14H22NO
Número de CAS:
61015-94-9
Peso molecular:
220.33
Número MDL:
MFCD16621409
Código UNSPSC:
12162002
ID de la sustancia en PubChem:
329763005

índice de refracción

n20/D 1.515

densidad

0.953 g/mL at 25 °C

temp. de almacenamiento

−20°C

cadena SMILES

CC(C)C(N([O])C(C)(C)C)c1ccccc1

InChI

1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3

Clave InChI

VGHCMXLEZFMZOZ-UHFFFAOYSA-N

Descripción general

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Aplicación

Block Copolymer Synthesis Using a Commercially Available NMP Inititator
Stable nitroxide radical useful in controlling living radical polymerizations

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Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Artículos

Block Copolymer Synthesis Using a Nitroxide-mediated Radical Polymerization (NMP) Approach

Block Copolymer Synthesis Using a Nitroxide-mediated Radical Polymerization (NMP) Approach

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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Protocolos

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Typical Procedures for Polymerizing via ATRP

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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