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Merck

449903

Sigma-Aldrich

Lithium fluoride

greener alternative

≥99.99% trace metals basis

Sinónimos:

Fluorolithium

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About This Item

Fórmula lineal:
LiF
Número de CAS:
Peso molecular:
25.94
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.23

grado

anhydrous

Nivel de calidad

Análisis

≥99.99% trace metals basis

formulario

powder and chunks

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

impurezas

≤100.0 ppm Trace Metal Analysis

bp

1673 °C/1 atm (lit.)

mp

845 °C (lit.)

solubilidad

aqueous acid: slightly soluble(lit.)

densidad

2.64 g/mL at 25 °C (lit.)

categoría alternativa más sostenible

cadena SMILES

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

Clave InChI

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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Descripción general

Lithium fluoride is a white crystalline solid with a high melting point. It is widely applied in the field of rechargeable batteries, storage devices, and thermoluminescent materials. LiF is also used as a coupling layer in OLED or PLED devices to enhance electron injection. On the other hand, it is preferred for optical applications due to its wide band gap, which allows it to transmit light efficiently.
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Aplicación

Lithium fluoride can be used:
  • As an additive to fabricate SiO@C/graphite composite anode materials for Li-ion batteries. LiF stabilizes solid electrolyte interphase (SEI) and enhances initial coulombic efficiency.
  • As a critical component in SEI for stabilizing the SEI layer and improving the cycling efficiency of Li metal batteries.
  • To fabricate electron contacts for high-efficiency n-type crystalline silicon solar cells.
  • To prepare solid-state light sources for radiation imaging detectors.
  • To synthesize highly crystalline MXene for asymmetric supercapacitor applications. And also, lightweight, flexible, and hydrophobic MXene foam with reasonable strength, high electrical conductivity, and an outstanding EMI-shielding performance.
  • As an electron-injection layer to fabricate ITO/PEDOT:PSS/perovskite/B3PYMPM/ LiF/Al OLED device with a quantum efficiency of 20%.

Pictogramas

Skull and crossbones

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Riesgos supl.

Código de clase de almacenamiento

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Radiat. Prot. Dosim., 66, 423-423 (1996)
Radiat. Prot. Dosim., 66, 101-101 (1996)
Zeinab Safari et al.
Nanomaterials (Basel, Switzerland), 9(11) (2019-11-21)
The performances of organometallic halide perovskite-based solar cells severely depend on the device architecture and the interface between each layer included in the device stack. In particular, the interface between the charge transporting layer and the perovskite film is crucial
Eur. J. Solid State Inorg. Chem., 33, 809-809 (1996)
R Takam et al.
Radiation protection dosimetry, 150(1), 22-33 (2011-08-30)
(6)LiF:Mg,Cu,P and (7)LiF:Mg,Cu,P glass-rod thermoluminescent dosemeters (TLDs) were used for measurements of out-of-field photon and neutron doses produced by Varian iX linear accelerator. Both TLDs were calibrated using 18-MV X-ray beam to investigate their dose-response sensitivity and linearity. CR-39 etch-track

Artículos

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Research and development of solid-state lithium fast-ion conductors is crucial because they can be potentially used as solid electrolytes in all-solid-state batteries, which may solve the safety and energy-density related issues of conventional lithium-ion batteries that use liquid (farmable organic) electrolytes.

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