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302937

Sigma-Aldrich

Perfluoro(methylcyclohexane)

technical grade, 90%

Sinónimos:

(Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane

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About This Item

Fórmula lineal:
C6F11CF3
Número de CAS:
355-02-2
Peso molecular:
350.05
Beilstein:
1915981
Número CE:
206-573-5
Número MDL:
MFCD00001468
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
24858283
NACRES:
NA.22

grado

technical grade

Nivel de calidad

100

Análisis

90%

formulario

liquid

índice de refracción

n17/D 1.285 (lit.)

bp

76 °C (lit.)

densidad

1.787 g/mL at 25 °C (lit.)

cadena SMILES

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F

InChI

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12

Clave InChI

QIROQPWSJUXOJC-UHFFFAOYSA-N

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Descripción general

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.

Aplicación

Perfluoro(methylcyclohexane) can be used as:
  • A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
  • A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.
Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Código de clase de almacenamiento

10 - Combustible liquids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Graeme R Kafka et al.
The journal of physical chemistry. A, 114(41), 11022-11026 (2010-09-30)
When refining structures using gas electron diffraction (GED) data, assumptions are often made in order to reduce the number of required geometrical parameters. Where these relate to light, peripheral atoms there is little effect on the refined heavy-atom structure, which
Mei-Jy Jeng et al.
Critical care medicine, 34(4), 1099-1105 (2006-02-18)
To investigate the therapeutic effects of bronchoalveolar lavage (BAL) with either diluted surfactant (SBAL) or perfluorochemical liquid (PBAL), followed by either conventional mechanical ventilation (CMV) or partial liquid ventilation (PLV), on lung injury and proinflammatory cytokine production induced by meconium
Miharu Koshino et al.
Ultrasonics sonochemistry, 54, 250-255 (2019-02-05)
We have developed a new emulsion template method for the synthesis of poly(methylmethacrylate) (PMMA) hollow nanoparticles with different sizes. This synthetic method involves sequential ultrasonic irradiation (20 kHz → 500 kHz → 1.6 MHz → 2.4 MHz → 5.0 MHz) for acoustic emulsification of a water-insoluble fluorous solvent such as perfluoromethylcyclohexane (PFMCH) in
S S Yang et al.
Biology of the neonate, 87(1), 60-65 (2004-10-07)
To test the hypothesis that intrapulmonary perfluorochemical (PFC) liquid may induce hypothermia, and to compare the effects of internal (IC), external (EC), and combined cooling techniques (EC + IC), 14 juvenile rabbits were randomized to EC by a cold blanket
Marco Adamo et al.
Soft matter, 14(10), 1759-1770 (2018-01-23)
The coupling of droplet microfluidics and Small Angle Neutron Scattering (SANS) is demonstrated with a range of model systems: isotopic solvent (H2O/D2O) mixtures, surfactant (sodium dodecyl sulfate, SDS) solutions and colloidal (silica) suspensions. Several droplet carrier phases are evaluated and
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