255025

Hexylmagnesium bromide solution

2.0 M in diethyl ether

• Sinónimos: 1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
• Fórmula lineal: CH₃(CH₂)₅MgBr
• Número de CAS: 3761-92-0
• Peso molecular: 189.38
• Beilstein: 3535624
• Número MDL: MFCD00000046
• Código UNSPSC: 12352103
• ID de la sustancia en PubChem: 24855279
• NACRES: NA.22

Propiedades

• Nivel de calidad: 100
• idoneidad de la reacción: reaction type: Grignard Reaction
• concentración: 2.0 M in diethyl ether
• densidad: 0.965 g/mL at 25 °C
• cadena SMILES: CCCCCC[Mg]Br
• InChI: 1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1
• Clave InChI: SFXUWNMDTWQSHE-UHFFFAOYSA-M

Descripción

Descripción general

Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.

Aplicación

Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.

Información de seguridad

• Pictogramas: GHS02,GHS05,GHS07
• Palabra de señalización: Danger
• Frases de peligro: H225,H260,H302,H314,H336
• Consejos de prudencia: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Clasificaciones de peligro: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Órganos de actuación: Central nervous system
• Riesgos supl.: EUH019
• Código de clase de almacenamiento: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): -40.0 °F - closed cup
• Punto de inflamabilidad (°C): -40 °C - closed cup
• Equipo de protección personal: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter