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Merck

221007

Sigma-Aldrich

Manganese(II) acetate tetrahydrate

≥99%

Sinónimos:

Manganese Diacetate Tetrahydrate, Manganous acetate

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About This Item

Fórmula lineal:
(CH3COO)2Mn · 4H2O
Número de CAS:
Peso molecular:
245.09
Beilstein:
3730728
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.23

Nivel de calidad

Análisis

≥99%

formulario

crystals

idoneidad de la reacción

core: manganese

mp

>300 °C (lit.)

densidad

1.589 g/mL at 25 °C (lit.)

cadena SMILES

[H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Mn]OC(C)=O

InChI

1S/2C2H4O2.Mn.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2

Clave InChI

CESXSDZNZGSWSP-UHFFFAOYSA-L

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Descripción general

Manganese(II) acetate tetrahydrate is an ionic compound soluble in water and polar solvents. It is commonly used as a precursor in chemical vapor deposition processes to fabricate cathode materials for lithium-ion batteries. It is also used as a sol-gel precursor to synthesize manganese oxide-based catalysts and other functional materials. Additionally, manganese(II) acetate tetrahydrate serves as a mordant in dyeing, a drier for paints and varnishes, and an oxidation catalyst. It is employed in the production of high-purity manganese dioxide, manganese oxide hydrate, and other manganese-containing compounds.

Aplicación

Manganese(ll) acetate tetrahydrate can be used as:     
  • A starting material in the synthesis of manganese carboxylates, which are used to prepare manganese oxide thin films by chemical vapor deposition (CVD).     
  • A precursor in the synthesis of manganese-TiO2 composites by chemical vapor condensation (CVC).These composites are used in the oxidation of NO at low temperatures.     
  • A precursor in preparation of NCM (LiNi1/3Co1/3Mn1/3O2) powder applicable as cathode material in lithium-ion batteries.     
  • A starting material for the synthesis of LiMn2O4 (LMO) film on Au substrate by sol-gel method.

Pictogramas

Health hazard

Palabra de señalización

Warning

Frases de peligro

Consejos de prudencia

Clasificaciones de peligro

Aquatic Chronic 3 - STOT RE 2 Inhalation

Órganos de actuación

Brain

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves


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Rechargeable metal-air batteries are considered a promising energy storage solution owing to their high theoretical energy density. The major obstacles to realising this technology include the slow kinetics of oxygen reduction and evolution on the cathode (air electrode) upon battery
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The composite metal oxide electrode films were fabricated using ex situ electrodeposition method with further heating treatment at 300°C. The obtained composite metal oxide film had a spherical structure with mass loading from 0.13 to 0.21 mg cm(-2). The structure

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