125903
1,3-Dibromopropane
ReagentPlus®, 99%
Synonym(s):
Trimethylene dibromide
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About This Item
Linear Formula:
Br(CH2)3Br
CAS Number:
Molecular Weight:
201.89
Beilstein:
635662
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21
vapor density
7 (vs air)
Quality Level
product line
ReagentPlus®
Assay
99%
form
liquid
refractive index
n20/D 1.524 (lit.)
bp
167 °C (lit.)
mp
−34 °C (lit.)
density
1.989 g/mL at 25 °C (lit.)
SMILES string
BrCCCBr
InChI
1S/C3H6Br2/c4-2-1-3-5/h1-3H2
InChI key
VEFLKXRACNJHOV-UHFFFAOYSA-N
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General description
1,3-Dibromopropane is a dihalogenated propane. It undergoes reduction catalyzed by electrogenerated solution-phase nickel(I) salen and nickel(I) salen confined in a polymer film on the surface of a carbon electrode to afford cyclopropane and propylene, respectively.
Application
1,3-Dibromopropane may be used in the preparation of chiral geminal dicationic ionic liquid and 1,3-bis(1-7′-chloro-4-quinolyl-4- piperazinyl)propane.3
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
129.2 °F - closed cup
Flash Point(C)
54 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Catalytic reduction of α,ω-dihaloalkanes with nickel (I) salen as a homogeneous-phase and polymer-bound mediator.
Dahm CE and Peters DG.
Journal of Electroanalytical Chemistry, 406(1), 119-129 (1996)
Synthesis of Chiral Geminal Dicationic Ionic Liquid from Amino Acids.
Yin A, et al.
Asian Journal of Chemistry, 25(12), 6721-6721 (2013)
E E Badr et al.
Journal of oleo science, 59(12), 647-652 (2010-11-26)
A fatty hydrazide based cationic gemini surfactants, 1,3-bis (N'-acyl-N,N-dimethylhydrazinium) propane dibromide which possess hydrolyzable amido moieties in the lipophilic portions, were prepared by reacting 1,3-bromopropane with N,N-dimethyl fatty hydrazide. The surface properties were explained and discussed based on the effect
A Witkowski et al.
The Journal of biological chemistry, 267(26), 18488-18492 (1992-09-15)
Thioesterase II is a 29-kDa monomer which, in certain specialized tissues, acts as a chain terminator in fatty acid synthesis by hydrolyzing medium-chain fatty acids from the fatty acid synthase. As with serine proteases, hydrolysis appears to involve acylation of
S P James et al.
Toxicology letters, 8(1-2), 7-15 (1981-04-01)
Oral administration of 1,3-dibromopropane (2 mmol/kg) to rats resulted in a marked decrease in the level of hepatic glutathione (GSH). Sulphur-containing [14C]-metabolites were excreted in the bile of rats dose with 1,3-bromo[14C]propane and were subjected to enterohepatic cycling. After an
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