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B89205

Sigma-Aldrich

tert-Butylamine

98%

Synonym(s):

TBA, 2-Amino-2-methylpropane

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About This Item

Linear Formula:
(CH3)3CNH2
CAS Number:
75-64-9
Molecular Weight:
73.14
Beilstein:
605267
EC Number:
200-888-1
MDL number:
MFCD00008050
UNSPSC Code:
12352100
PubChem Substance ID:
24892107
NACRES:
NA.22

vapor density

2.5 (vs air)

Quality Level

100
300

vapor pressure

5.7 psi ( 20 °C)

Assay

98%

form

liquid

autoignition temp.

716 °F

expl. lim.

9.8 %

refractive index

n20/D 1.377 (lit.)

bp

46 °C (lit.)

mp

−67 °C (lit.)

density

0.696 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)N

InChI

1S/C4H11N/c1-4(2,3)5/h5H2,1-3H3

InChI key

YBRBMKDOPFTVDT-UHFFFAOYSA-N

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General description

tert-Butylamine is an organic chemical compound used as an intermediate in the synthesis of sulfenamides.

Application

tert-Butylamine (TBA) can be used in the following applications:
  • It is an effective solvent for the removal of surfactants such as PVP and capping agents such as KBr from the nanoparticle surface.
  • Mixed complexes of platinum, amino acid and TBA show potent anti-tumor activities.
  • It is an effective base for the aziridination of 2-arylethenyl(diphenyl)sulfonium salt to form the corresponding N-tert-butylaziridine.

Signal Word

Danger

Hazard Statements

H225,H302,H314,H331,H412

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

-36.4 °F - closed cup

Flash Point(C)

-38 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP0863
SHBP0291
SHBN9440
SHBN8809
SHBN8810

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Antitumor complexes of platinum with carrier molecules. 2 [1]. Mixed complexes of amino acids and tert-butylamine.
Bersanetti E, et al.
Inorgorganica Chimica Acta, 93(4), 167-172 (1984)
Removal of surfactant and capping agent from Pd nanocubes (Pd-NCs) using tert-butylamine: its effect on electrochemical characteristics.
Naresh N, et al.
Journal of Material Chemistry A, 1(30), 8553-8559 (2013)
A convenient method for the synthesis of 2-arylaziridines from styrene derivatives via 2-arylethenyl (diphenyl) sulfonium salts.
Matsuo J I, et al.
Chemistry Letters (Jpn), 32(4), 392-393 (2003)
Antitumor complexes of platinum with carrier molecules. 3. Cytotoxicity of some platinum amino acid complexes against cisplatin-sensitive and resistant L1210 leukemia cells.
Colombo A, et al.
Inorgorganica Chimica Acta, 125(1), L1-L3 (1986)
A R Ekkati et al.
Amino acids, 38(3), 747-751 (2009-04-01)
N-Acetyl-AA(amino acid)-NHtBu derivatives of all 20 naturally occurring amino acids have been synthesized. Syntheses were performed via solution-phase methodology with yields that allow for access to gram quantities of substrates, in most cases. Syntheses include the coupling of a hindered
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