Skip to Content
Merck
All Photos(1)

Key Documents

More Documents

ALD00608

Sigma-Aldrich

Ni(bpy)3Br2

Synonym(s):

Trisbipyridylnickel dibromide

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C30H24Br2N6Ni
Molecular Weight:
687.05
UNSPSC Code:
12352300

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

Ni(bpy)3Br2 is a Ni precatalyst shown by the Baran Lab to be an effective catalyst for the electrochemical amination (e-amination) of arly halides with amines.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

Other Notes

Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications

related product

Product No.
Description
Pricing

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Yu Kawamata et al.
Journal of the American Chemical Society, 141(15), 6392-6402 (2019-03-25)
C-N cross-coupling is one of the most valuable and widespread transformations in organic synthesis. Largely dominated by Pd- and Cu-based catalytic systems, it has proven to be a staple transformation for those in both academia and industry. The current study

Related Content

Baran Group – Professor Product Portal

The Baran Group works with Sigma-Aldrich in providing a portfolio of zinc-based reagents promoting difluoromethylation, trifluoromethylation, trifluoroethylation and isopropylation of aryl and heteroaryl motifs. Baran’s lab has also helped introduce a portable desaturase (Tz0Cl), which promotes the installation of alcohol and amine groups and leaves behind a highly useful tosyl group for further transformations.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service