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341630

Sigma-Aldrich

Chloro(pyridine)bis(dimethylglyoximato)cobalt(III)

Synonym(s):

Chloro(pyridine)cobaloxime(III), NSC 175756

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About This Item

Empirical Formula (Hill Notation):
C13H19ClCoN5O4
CAS Number:
23295-32-1
Molecular Weight:
403.71
MDL number:
MFCD00075236
UNSPSC Code:
12161600
PubChem Substance ID:
24860975
NACRES:
NA.22

Quality Level

100

reaction suitability

core: cobalt
reaction type: Photocatalysis
reagent type: catalyst

mp

235 °C (dec.) (lit.)

SMILES string

c1ccncc1.CC(=N\O)\C(C)=N/O[Co](Cl)O\N=C(C)/C(C)=N\O

InChI

1S/C5H5N.2C4H8N2O2.ClH.Co/c1-2-4-6-5-3-1;2*1-3(5-7)4(2)6-8;;/h1-5H;2*7-8H,1-2H3;1H;/q;;;;+3/p-3/b;2*5-3-,6-4-;;

InChI key

CKWAWSVVCRVWHW-PCJYWUFNSA-K

Application

Catalyst for:
  • Photocatalytic H2 generation from water under visible light
  • Doetz benzannulation reaction
  • Proton electroreduction reactions
  • Radical heterocyclization reactions
  • Preparation of Mannich base analogues
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN4900
MKCL4232
MKCJ6190
MKCG7509
MKCD1808

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Agnès Barbance et al.
Frontiers in microbiology, 11, 590061-590061 (2020-11-27)
Chlordecone (Kepone®) and γ-hexachlorocyclohexane (γ-HCH or lindane) have been used for decades in the French West Indies (FWI) resulting in long-term soil and water pollution. In a previous work, we have identified a new Citrobacter species (sp.86) that is able

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