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Key Documents

333875

Sigma-Aldrich

Zinc tetrafluoroborate hydrate

Synonym(s):

Zinc ditetrafluoroborate hydrate

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About This Item

Linear Formula:
Zn(BF4)2·xH2O
CAS Number:
Molecular Weight:
239.00 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

form

crystalline

composition

Degree of hydration, 6-7

reaction suitability

reagent type: catalyst
core: zinc

SMILES string

O.[Zn++].F[B-](F)(F)F.F[B-](F)(F)F

InChI

1S/2BF4.H2O.Zn/c2*2-1(3,4)5;;/h;;1H2;/q2*-1;;+2

InChI key

WKVXCUNBQMAPGE-UHFFFAOYSA-N

Application

Starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properites.

Pictograms

CorrosionSkull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Timothy C. Higgs et al.
Inorganic chemistry, 37(9), 2263-2272 (2001-10-24)
The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O)(4)](2+), where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+). Each of these complexes has been structurally

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