Skip to Content
Merck
All Photos(2)

Key Documents

241725

Sigma-Aldrich

Triisopropylsilyl chloride

97%

Synonym(s):

Chlorotriisopropylsilane, TIPSCl, Triisopropylchlorosilane, Triisopropylsilyl chloride

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
[(CH3)2CH]3SiCl
CAS Number:
Molecular Weight:
192.80
Beilstein:
1737446
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

1.16 mmHg ( 20 °C)

Assay

97%

form

liquid

refractive index

n20/D 1.452 (lit.)

bp

198 °C/739 mmHg (lit.)

density

0.901 g/mL at 25 °C (lit.)

SMILES string

CC(C)[Si](Cl)(C(C)C)C(C)C

InChI

1S/C9H21ClSi/c1-7(2)11(10,8(3)4)9(5)6/h7-9H,1-6H3

InChI key

KQIADDMXRMTWHZ-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Use of TIPS substituted alkynes in a preparation of silyl vinyl ketenes from chromium carbene complexes.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

147.2 °F - closed cup

Flash Point(C)

64 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

William H Moser et al.
The Journal of organic chemistry, 71(17), 6542-6546 (2006-08-12)
Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl-substituted alkynes. The ability of these silyl vinylketenes to participate with carbenoid reagents in [4 + 1] annulation reactions was investigated. The best results
Greene, T.W. Wuts, P.G.M.
Protective Groups in Organic Synthesis (1991)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service