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227463

Sigma-Aldrich

1,1′-(Methylenedi-4,1-phenylene)bismaleimide

95%

Synonym(s):

Bismaleimide

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About This Item

Empirical Formula (Hill Notation):
C21H14N2O4
CAS Number:
13676-54-5
Molecular Weight:
358.35
EC Number:
237-163-4
MDL number:
MFCD00005507
UNSPSC Code:
12352100
PubChem Substance ID:
24853634
NACRES:
NA.22

Assay

95%

form

powder

mp

156-158 °C (lit.)

SMILES string

O=C1C=CC(=O)N1c2ccc(Cc3ccc(cc3)N4C(=O)C=CC4=O)cc2

InChI

1S/C21H14N2O4/c24-18-9-10-19(25)22(18)16-5-1-14(2-6-16)13-15-3-7-17(8-4-15)23-20(26)11-12-21(23)27/h1-12H,13H2

InChI key

XQUPVDVFXZDTLT-UHFFFAOYSA-N

General description

The thermal and mechanical properties of GEEA cured by 1,1′-(methylenedi-4,1-phenylene)bismaleimide were studied. MDP-BMI is a cross-linking agent widely used in the synthesis of thermosetting polymers and flame retardant resins.

Application

1,1′-(Methylenedi-4,1-phenylene)bismaleimide was used to cure glycidyl ester of eleostearic acid (GEEA).

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H315,H319,H330,H335

Hazard Classifications

Acute Tox. 2 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Seon Min Woo et al.
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Biomacromolecules, 15(3), 837-843 (2014-02-04)
A novel biobased epoxy monomer with conjugated double bonds, glycidyl ester of eleostearic acid (GEEA) was synthesized from tung oil fatty acids and characterized by (1)H and (13)C NMR. Differential scanning calorimeter analysis (DSC) and Fourier transform infrared spectroscopy (FT-IR)
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