Skip to Content
Merck
All Photos(1)

Key Documents

429112

Sigma-Aldrich

2-Bromo-6-methylpyridine

98%

Synonym(s):

2-Bromo-6-picoline, 2-Methyl-6-bromopyridine, 6-Bromo-2-methylpyridine, 6-Bromo-2-picoline, 6-Methyl-2-bromopyridine

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C6H6BrN
CAS Number:
Molecular Weight:
172.02
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

liquid

refractive index

n20/D 1.562 (lit.)

bp

102-103 °C/20 mmHg (lit.)

density

1.512 g/mL at 25 °C (lit.)

functional group

bromo

SMILES string

Cc1cccc(Br)n1

InChI

1S/C6H6BrN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3

InChI key

SOHDPICLICFSOP-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

2-Bromo-6-methylpyridine is a bromopyridine derivative. It is formed when 2-chloro-6-methylpyridine is heated with bromotrimethylsilane. Its synthesis from various methods have been reported.

Application

2-Bromo-6-methylpyridine may be used in the synthesis of the following:
  • 6,6′-dimethyl-2,2′-bipyridine
  • 6-methyl-2-pyridyl-2-pyridylmethanone
  • 2-methyl-6-(trimethylsilyl)-pyridine
  • N,N′-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy)
  • 2-methyl-6-(trimethylstannanyl)pyridine
  • 2-(6-methylpyridin-2-yl)propan-2-ol
  • bis[(2-bromo-6-methylpyridinium)hexafluorosilicate] monohydrate

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

206.6 °F - closed cup

Flash Point(C)

97 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu (I) complexation.
2Eisenbach CD, et al.
Macromolecular Chemistry and Physics, 196(4), 1077-1091 (1995)
Catalytic Asymmetric Synthesis of Bis-armed Aromatic Amino Acid Derivatives. Problems Related to the Synthesis of Enantiomerically Pure Bis-methyl Ester of the (S,S)-Pyridine-2,6-diyl Bis-alanine.
Basu B and FrejdT T.
Acta Chemica Scandinavica, 50, 316-322 (1996)
Nickel complexes with new bidentate P,N phosphinitooxazoline and-pyridine ligands: Application for the catalytic oligomerization of ethylene.
Speiser F, et al.
Inorganic Chemistry, 43(5), 1649-1658 (2004)
Preparation, structure and properties of pyridinium/bipyridinium hexafluorosilicates.
Gelmboldt VO, et al.
Journal of Fluorine Chemistry, 160, 57-63 (2014)
Synthesis of Dimethylbipyridines by the Reductive Coupling of 2-Halomethylpyridines with Nickel Catalyst.
Rajalakshmanan E and Alexander V.
Synthetic Communications, 35(6), 891-895 (2005)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service