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146617

Sigma-Aldrich

Bathophenanthrolinedisulfonic acid disodium salt hydrate

98%

Synonym(s):

Bathophenanthrolinedisulfonic acid disodium salt trihydrate, 4,7-Diphenyl-1,10-phenanthroline-disulfonic acid disodium salt trihydrate, Disodium bathophenanthrolinedisulfonate trihydrate

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About This Item

Empirical Formula (Hill Notation):
C24H14N2Na2O6S2 · 3H2O
CAS Number:
52746-49-3
Molecular Weight:
590.53
EC Number:
258-152-0
UNSPSC Code:
12352100
NACRES:
NA.22

Quality Level

100

Assay

98%

form

powder

mp

300 °C

solubility

water: soluble 100 mg/mL, clear to slightly hazy, yellow (to red)

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General description

Bathophenanthrolinedisulfonic acid disodium salt forms water soluble complexes with palladium and their catalytic role in oxidation of 2-hexanol has been examined.

Application

Bathophenanthrolinedisulfonic acid disodium salt hydrate was used in the preparation of anionic Europium(III) disulfonated bathophenanthroline tris(dibenzoylmethanate) complex.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Intercalation of luminescent Europium (III) complexes in layered double hydroxides.
Sarakha L, et al.
Opt. Mater., 31(3), 562-566 (2009)
Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium-Neocuproine Catalyzed Aerobic Oxidation of Alcohols in Aqueous Solvents#.
Brink GJ, et al.
Advanced Synthesis & Catalysis, 345(12), 1341-1352 (2003)
A Paolicchi et al.
Journal of investigative medicine : the official publication of the American Federation for Clinical Research, 47(3), 151-160 (1999-04-13)
gamma-Glutamyl transpeptidase (gamma-GT) is found in serum and in the plasma membranes of virtually all cell types. Its physiologic role is to initiate the hydrolysis of extracellular glutathione (GSH), a tripeptide in which cysteine lies between alpha-glycine and gamma-glutamate residues.
Simone Zanarini et al.
The journal of physical chemistry. B, 112(33), 10188-10193 (2008-07-26)
In this work, the electrochemical and ECL properties of tris[1,10-phenanthrolinediyl-4,7-di(benzenesulfonate)]Ru(II) ([Ru(BPS)3]4-) have been addressed in both strictly aprotic conditions and aqueous buffers. A combined theoretical and experimental approach is presented to focus thermodynamics and kinetic effects of electro-generated species possessing
J M May et al.
Biochemical pharmacology, 57(11), 1275-1282 (1999-05-07)
The role of ascorbic acid in transferrin-independent ferric iron reduction and uptake was evaluated in cultured U-937 monocytic cells. Uptake of 55Fe by U-937 cells was doubled by 100 microM extracellular ascorbate, and by pre-incubation of cells with 100 microM
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