698717
Polyoxyethanyl-α-tocopheryl sebacate
15 wt. % in H2O
Synonym(s):
PTS
About This Item
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form
liquid
mol wt
~1,200
reaction suitability
reaction type: C-C Bond Formation
greener alternative product characteristics
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concentration
15 wt. % in H2O
greener alternative category
General description
Application
Uses:
- Provides an aqueous micellar environment for transition metal-catalyzed Heck coupling, cross metathesis and ring closing metathesis reactions
- Surfactant for catalytic asymmetric Baeyer-Villiger oxidation in water using PtII catalysts and hydrogen peroxide
- Orally active CoQ10 carrier for neuroprotection after stroke or cardiac arrest
Legal Information
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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Articles
Micellular catalysis has provided the ability to carry out several commonly used transformations used in the synthetic community to be carried out in water.
The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.
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Prof. Bruce Lipshutz and co-workers have developed designer surfactants to allow several classes of transformations (e.g. Suzuki-Miyaura, Olefin Metathesis, 1,4-Addition to Enones, etc.) to be performed in water.
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