Skip to Content
Merck
All Photos(2)

Key Documents

More Documents

682500

Sigma-Aldrich

Copper(I) thiophene-2-carboxylate

Synonym(s):

(2-Thiophenecarboxylato)copper, 2-Thiophenecarboxylic acid, copper complex, Cu (TC), Cuprous 2-thiophenecarboxylate

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C5H3CuO2S
CAS Number:
68986-76-5
Molecular Weight:
190.69
MDL number:
MFCD02183524
UNSPSC Code:
12161600
PubChem Substance ID:
24885718
NACRES:
NA.22

form

solid

reaction suitability

core: copper
reaction type: C-C Bond Formation
reagent type: catalyst

SMILES string

[Cu]OC(=O)c1cccs1

InChI

1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1

InChI key

SFJMFSWCBVEHBA-UHFFFAOYSA-M

Application

Copper(I) thiophene-2-carboxylate can be used as a reactant or reagent in:
  • Studies of xenobiotic response to herbicide safener derivatives.
  • Synthesis of functionalized BODIPY dye analogs.
  • Orthogonal cross-coupling reactions.
  • Preparation of parent borondipyrromethene system.
  • Copper mediated cross-coupling.

Reactant or reagent involved in:
  • Studies of xenobiotic response to herbicide safener derivatives
  • Synthesis of functionalized BODIPY dye analogs
  • Orthogonal cross-coupling reactions
  • Preparation of parent borondipyrromethene system
  • Copper mediated cross-coupling

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Xenobiotic responsiveness of Arabidopsis thaliana to a chemical series derived from a herbicide safener.
Skipsey M, et al.
The Journal of Biological Chemistry, 286(37), 32268-32276 (2011)
The smallest and one of the brightest. Efficient preparation and optical description of the parent borondipyrromethene system.
Arroyo I J, et al.
The Journal of Organic Chemistry, 74(15), 5719-5722 (2009)
Regioselective Syntheses of 2, 3?Substituted Pyridines by Orthogonal Cross?Coupling Strategies.
Koley M, et al.
European Journal of Organic Chemistry, 2011(10), 1972-1979 (2011)
2?and 3?Monohalogenated BODIPY Dyes and Their Functionalized Analogues: Synthesis and Spectroscopy.
Leen V, et al.
European Journal of Organic Chemistry, 2011(23), 4386-4396 (2011)
N-Amidation by copper-mediated cross-coupling of organostannanes or boronic acids with O-acetyl hydroxamic acids.
Zhang Z, et al.
Organic Letters, 10(14), 3005-3008 (2008)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service