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148504

Sigma-Aldrich

Triphenylsilane

97%

Synonym(s):

1,1′,1′′-Silylidynetrisbenzene, NSC 12565, Triphenylhydrosilane

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About This Item

Linear Formula:
(C6H5)3SiH
CAS Number:
789-25-3
Molecular Weight:
260.41
Beilstein:
978182
EC Number:
212-333-0
MDL number:
MFCD00003003
UNSPSC Code:
12352002
PubChem Substance ID:
24848907
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

reagent type: reductant

bp

152 °C/2 mmHg (lit.)

mp

43-45 °C (lit.)

SMILES string

c1ccc(cc1)[SiH](c2ccccc2)c3ccccc3

InChI

1S/C18H16Si/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H

InChI key

AKQNYQDSIDKVJZ-UHFFFAOYSA-N

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Application

Reactant or reagent:
  • For catalytic hydrogen deuterium exchange reactions of silanes
  • To be oxidized by carbon nanotube-gold nanohybrids
  • For hydrolysis by ruthenium complexes
  • For hydrosilylation to produce enolsilanes
  • For synthesis of bromosilanes
  • For ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives
  • Used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

168.8 °F - closed cup

Flash Point(C)

76 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP4295
MKCH1001
MKCH1658
MKCF7958
MKCC5831

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Sylwia Członka et al.
Materials (Basel, Switzerland), 13(7) (2020-04-16)
In this work, rigid polyurethane (PUR) foams were prepared by incorporating 2 wt% of eucalyptus fibers. The eucalyptus fibers were surface-modified by maleic anhydride, alkali, and silane (triphenylsilanol) treatment. The impact of the modified eucalyptus fibers on the mechanical, thermal
Courtney M Olson et al.
The Journal of chemical physics, 147(12), 124302-124302 (2017-10-02)
Fourier transform infrared and two-dimensional IR (2D-IR) spectroscopies were applied to two different silanes in three different solvents. The selected solutes exhibit different degrees of vibrational solvatochromism for the Si-H vibration. Density functional theory calculations confirm that this difference in

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