208043

Natriumsulfid Nonahydrat

ACS reagent, ≥98.0%

• Lineare Formel: Na₂S·9H₂O
• CAS-Nummer: 1313-84-4
• Molekulargewicht: 240.18
• EG-Nummer: 215-211-5
• MDL-Nummer: MFCD00149184
• UNSPSC-Code: 12352302
• PubChem Substanz-ID: 329752036
• NACRES: NA.21

Eigenschaften

• Qualität: ACS reagent
• Assay: ≥98.0%
• Form: crystals or chunks
• Eignung der Reaktion: reagent type: catalyst; core: sodium
• Farbe: colorless to slightly yellow
• Anionenspuren: SO₃^2- and S₂O₃^2-: ≤0.1%
• Kationenspuren: Fe:, passes test; NH₄⁺: ≤0.005%
• Lagertemp.: 2-8°C
• SMILES String: O.O.O.O.O.O.O.O.O.[Na]S[Na]
• InChI: 1S/2Na.9H2O.S/h;;9*1H2;
• InChIKey: UIINQVYGFKNSPA-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Sodium sulfide nonahydrate participates in the conversion of nitroxides to amines, via reduction.

Anwendung

Sodium sulfide nonahydrate has been used as a source of H₂S, to study the effect of H₂S on amyloid fibrils associated with neurodegenerative diseases. It has been used in the preparation of sulfide standards for the quantitative analysis of sulfides in raw wastewater (sewage) samples.
It serves as a catalyst during synthesis of thioamides.

Sodium sulfide nonahydrate has been used as a standard for the quantification of volatile sulfur compounds in cheese samples by gas chromatography. It reacts with 4-(2′-hydroxyaryl)-2-(N,N-dialkylamino)-1,3-dithiolium perchlorates in ethanol at room temperature and boiling ethanol to form 1,3-dithiole-2-thiones and 2′-hydroxyacetophenones, respectively. Sodium sulfide nonahydrate may be used as a reducing agent for the conversion of vic-dibromides to the corresponding olefins via reductive debromination.

Sicherheitshinweise

• Piktogramme: GHS06,GHS05,GHS09
• Signalwort: Danger
• H-Sätze: H302,H311,H314,H410
• P-Sätze: P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable