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Merck

92330

Sigma-Aldrich

Trimethylborat

purum, ≥99.0% (GC)

Synonym(e):

Borsäure-trimethylester, Methylborat

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About This Item

Lineare Formel:
B(OCH3)3
CAS-Nummer:
Molekulargewicht:
103.91
Beilstein:
1697939
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22

Dampfdichte

3.59 (vs air)

Qualitätsniveau

Qualität

purum

Assay

≥99.0% (GC)

Form

liquid

Brechungsindex

n20/D 1.346 (lit.)
n20/D 1.358

bp

68-69 °C (lit.)

mp (Schmelzpunkt)

−34 °C (lit.)

Dichte

0.932 g/mL at 20 °C (lit.)

SMILES String

COB(OC)OC

InChI

1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3

InChIKey

WRECIMRULFAWHA-UHFFFAOYSA-N

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Anwendung

Trimethyl borate (TMB) can be used:
  • For the synthesis of luminogens having triphenylamine core and tetraphenylethene peripheral moieties.
  • For the synthesis of ammonia borane and trialkylamine boranes.
  • In the reduction of carboxylic acids in the presence of borane-methyl sulfide.
  • As a reagent to crosslink phopshate complexes.
  • As a source of boron to synthesize boron nitride nanotubes by chemical vapor deposition (CVD) method.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - STOT SE 1

Zielorgane

Eyes

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

12.2 °F - (own results)

Flammpunkt (°C)

-11 °C - (own results)

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Organic synthesis using borane-methyl sulfide. II. Reduction of aromatic carboxylic acids in the presence of trimethyl borate.
Lane CF, et al.
The Journal of Organic Chemistry, 39(20), 3052-3054 (1974)
One-Pot Synthesis of Ammonia-Borane and Trialkylamine-Boranes from Trimethyl Borate.
Veeraraghavan RP, et al.
Organic Letters, 14(24), 6119-6121 (2012)
Thermal-heating CVD synthesis of BN nanotubes from trimethyl borate and nitrogen gas.
Lin FH, et al.
Materials Chemistry and Physics, 107(1), 115-121 (2008)
A Colorado et al.
Journal of mass spectrometry : JMS, 31(4), 403-410 (1996-04-01)
Barbiturates are a class of drugs that are utilized as anesthetics and sleeping agents and are used for the treatment of anxiety, epilepsy and other psychiatric disorders. Because of their pyrimidine structures, barbiturates are highly basic compounds. The evaluation of
Changing the Behavior of Chromophores from Aggregation?Caused Quenching to Aggregation?Induced Emission: Development of Highly Efficient Light Emitters in the Solid State.
Yuan W Z, et al.
Advanced Materials, 22(19), 2159-2163 (2010)

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