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Merck

32979

Supelco

Acetamiprid-N-desmethyl

PESTANAL®, analytical standard

Synonym(e):

N-(6-Chlor-3-pyridylmethyl)-N′-cyan-acetamidin

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About This Item

Empirische Formel (Hill-System):
C9H9ClN4
CAS-Nummer:
Molekulargewicht:
208.65
MDL-Nummer:
UNSPSC-Code:
41116107
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Produktlinie

PESTANAL®

Haltbarkeit

limited shelf life, expiry date on the label

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Anwendung(en)

agriculture
environmental

Format

neat

SMILES String

C\C(NCc1ccc(Cl)nc1)=N/C#N

InChI

1S/C9H9ClN4/c1-7(14-6-11)12-4-8-2-3-9(10)13-5-8/h2-3,5H,4H2,1H3,(H,12,14)

InChIKey

AYEAUPRZTZWBBF-UHFFFAOYSA-N

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Allgemeine Beschreibung

Acetamiprid-N-desmethyl is a metabolite of the neonicotinoid insecticide, acetamiprid.

Anwendung

Acetamiprid-N-desmethyl may be used as a reference standard in the determination of acetamiprid-N-desmethyl in urine samples using ultra high-performance liquid chromatography coupled with orbitrap high resolution mass spectrometry (UHPLC-HRMS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Sonstige Hinweise

Acetamiprid-Metabolit IM-2-1

Empfohlene Produkte

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Rechtliche Hinweise

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Piktogramme

Skull and crossbones

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Analysenzertifikate (COA)

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Kunden haben sich ebenfalls angesehen

Slide 1 of 6

1 of 6

Relationship between urinary N-desmethyl-acetamiprid and typical symptoms including neurological findings: a prevalence case-control study
Marfo TJ, et al.
PLoS ONE, 10(11), e0142172-e0142172 (2015)
Richard C Kolanczyk et al.
Xenobiotica; the fate of foreign compounds in biological systems, 50(7), 805-814 (2019-11-15)
Providing an alternative to pyrethroids, organophosphates, and carbamates, the neonicotinoids are now the most widely used insecticides in the world. They are water soluble and relatively stable in soil and water which allows for run-off through surface waters and thus
Takamitsu Otake et al.
Journal of AOAC International, 103(6), 1469-1477 (2020-11-29)
Neonicotinoid insecticides (neonicotinoids) are widely used, however, they can negatively affect human health. Thus, neonicotinoids and their metabolites in human urine are analyzed globally to assess exposure levels and health risks. To properly assess the exposure levels and health risks
Mohammad Faraji et al.
Food chemistry, 240, 634-641 (2017-09-28)
A QuEChERS based methodology was developed for the simultaneous identification and quantification of acetamiprid, imidacloprid, and spirotetramat and their relevant metabolites in pistachio by liquid chromatography-tandem mass spectrometry for the first time. First, sample extraction was done with MeCN:citrate buffer:NaHCO
Jianbo Hou et al.
Food chemistry, 270, 204-213 (2018-09-04)
An analytical method based on liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for the first simultaneous determination of ten neonicotinoid insecticides (pymetrozine, dinotefuran, nitenpyram, thiamethoxam, flonicamid, imidacloprid, clothianidin, imidaclothiz, acetamiprid, thiacloprid) and two metabolites (4-trifluoromethylnicotinamide and N-desmethylacetamiprid) in honey

Protokolle

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

On Friday, April 27, 2018, the European Union decided to ban the use of three neonicotinoid insecticides from use on field crops, having deemed them dangerous to bees. This application demonstrates the analysis of these banned compounds and others from dandelion blossoms using QuEChERS and LC-MS.

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