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Merck

01713

Sigma-Aldrich

Kryolith

synthetic, ≥97.0% (from F)

Synonym(e):

Natriumhexafluoroaluminat

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About This Item

Lineare Formel:
Na3AlF6
CAS-Nummer:
Molekulargewicht:
209.94
MDL-Nummer:
UNSPSC-Code:
12161600
PubChem Substanz-ID:
NACRES:
NA.22

Qualitätsniveau

Assay

≥97.0% (from F)

Form

powder

Qualität

synthetic

Eignung der Reaktion

core: aluminum
reagent type: catalyst

Verunreinigungen

≤0.5% silicic acid (as SiO2)

Verlust

≤0.5% loss on drying, 105 °C

Kationenspuren

Fe: ≤500 mg/kg

Lagertemp.

2-30°C

SMILES String

[Na+].[Na+].[Na+].F[Al-3](F)(F)(F)(F)F

InChI

1S/Al.6FH.3Na/h;6*1H;;;/q+3;;;;;;;3*+1/p-6

InChIKey

REHXRBDMVPYGJX-UHFFFAOYSA-H

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Anwendung

Cryolite is commonly used as an electrolyte for aluminum electrolysis. Alumina is dissolved in molten cryolite is used to dissolve alumina during aluminium processing.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - STOT RE 1

Lagerklassenschlüssel

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Effects of airborne fluorides on workers at a cryolite production plant.
Y Baba et al.
Gaoxiong yi xue ke xue za zhi = The Kaohsiung journal of medical sciences, 1(4), 226-233 (1985-04-01)
Tone Sjåheim et al.
American journal of industrial medicine, 50(6), 443-448 (2007-05-12)
Aluminum potroom asthma (PA) has been described in several reports. This study aimed to investigate the association between blood eosinophils and PA. In a cross-sectional study, 338 workers were examined as follows: spirometry, blood eosinophils, skin prick test, and work
Extended follow-up of cancer incidence in fluoride-exposed workers.
Philippe Grandjean et al.
Journal of the National Cancer Institute, 96(10), 802-803 (2004-05-20)
Liangshi Wang et al.
Journal of hazardous materials, 209-210, 77-83 (2012-01-28)
This paper investigates the development of a new environment friendly approach for treatment of bastnasite. A new process was developed to recover fluorine from bastnasite as synthetic cryolite by-product. The conditions affecting the fluorine removal and recovery in the process
T K Semennikova et al.
Gigiena truda i professional'nye zabolevaniia, (3)(3), 6-8 (1992-01-01)
Over 1000 workers of hydrofluoric and cryolite enterprises and electrolysis shops of aluminium enterprises were examined. Subjects exposed to soluble hydrofluorides presented in the early stage of chronic intoxication with a variety of syndromes, that was characteristic of intoxication with

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