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Wichtige Dokumente
V1902
Vinylbromid
98%
Synonym(e):
Bromethylen
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About This Item
Lineare Formel:
CH2=CHBr
CAS-Nummer:
Molekulargewicht:
106.95
Beilstein:
1361370
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12162002
PubChem Substanz-ID:
NACRES:
NA.23
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Dampfdichte
3.8 (15 °C, vs air)
Qualitätsniveau
Dampfdruck
1551 mmHg ( 37.8 °C)
Assay
98%
Selbstzündungstemp.
986 °F
Enthält
200 ppm monomethyl ether hydroquinone as inhibitor
Expl.-Gr.
15 %
bp
16 °C/750 mmHg (lit.)
mp (Schmelzpunkt)
−139 °C (lit.)
Dichte
1.517 g/mL at 25 °C (lit.)
Lagertemp.
2-8°C
SMILES String
BrC=C
InChI
1S/C2H3Br/c1-2-3/h2H,1H2
InChIKey
INLLPKCGLOXCIV-UHFFFAOYSA-N
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Verwandte Kategorien
Anwendung
- FTIR and Raman Spectroscopy Study of Soot Deposits: Investigates soot formation during the infrared multiphoton dissociation of vinyl bromide, suggesting potential applications in materials science regarding soot characteristics (Samoudi et al., 2022).
- Nickel-Catalyzed Reductive Cross-Coupling: Describes a method for coupling vinyl bromides with unactivated alkyl halides, highlighting its utility in synthetic organic chemistry for creating complex molecules (Gong et al., 2017).
- Silver-Promoted Synthesis of Vinyl Sulfones: This study explores the reactivity of vinyl bromides with sulfonyl hydrazides under aqueous conditions, applicable to pharmaceutical synthesis due to the biorelevance of sulfones (Zhang et al., 2020).
- Visible Light on Vinyl Halides: Examines the photocatalytic properties of vinyl bromides, which could influence the development of green chemistry applications (Pagire et al., 2020).
- Palladium Catalyzed Cross-Coupling of Diboronates: Focuses on the reactions of vinyl bromides with diboronates, offering insights into new methodologies for constructing biologically active compounds (Li et al., 2014).
Sonstige Hinweise
V1902-100 g, V1902-900 g, and 1902-2.2 kg includes installed 316SS needle valve.
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Stainless steel hose adapter Z146838 or stainless steel body mini gas regulator Z513547 is recommended.
Regulierungsbehörde
Produkt-Nr.
Beschreibung
Preisangaben
Schlaucholive
Produkt-Nr.
Beschreibung
Preisangaben
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Acute Tox. 4 Oral - Carc. 1B - Flam. Gas 1A - Press. Gas Liquefied gas
Lagerklassenschlüssel
2A - Gases
WGK
WGK 3
Flammpunkt (°F)
55.4 °F
Flammpunkt (°C)
13 °C
Persönliche Schutzausrüstung
Eyeshields, Faceshields, Gloves
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With the catalysis of CuI/trans-N,N'-dimethylcyclohexane-1,2-diamine, a number of carboxylic acids underwent efficient intramolecular O-vinylation with vinyl bromides leading to the synthesis of the corresponding five- and six-membered enol lactones. The same catalytic system also led to the efficient cycloisomerization of
Qiwu Zhao et al.
Organic letters, 10(18), 4037-4040 (2008-08-30)
A general and highly efficient synthesis of 4-alkylidene-2-azetidinones was achieved by the Cu(I)-catalyzed intramolecular C-N coupling of amides with vinyl bromides. This 4-exo ring closure was found to be fundamentally preferred over other modes (5-exo, 6-exo, and 6-endo) of cyclization
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Piotr Pawluć et al.
Organic letters, 11(15), 3390-3393 (2009-07-04)
A new, efficient protocol for the highly stereoselective one-pot synthesis of (E)-beta-aryl vinyl iodides and (E)-beta-aryl vinyl bromides from styrenes based on sequential ruthenium-catalyzed silylative coupling-N-halosuccinimide-mediated halodesilylation reactions is reported.
Cheon-Gyu Cho et al.
Organic letters, 7(16), 3569-3572 (2005-07-29)
An effective, readily scalable two-step synthesis of trisubstituted (E)-vinyl bromides involving bromination of alpha,beta-unsaturated lactones followed by hydrolytic fragmentation has been developed. Several trisubstituted (E)-vinyl bromides, including multigram quantities of (+)-(E)-4-bromo-2-methyl-3-pentenol, a synthetic intermediate required for the C(8)-C(11) moieties of
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