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D187208

Sigma-Aldrich

2,5-Dimethyltetrahydrofuran, Mischung aus cis und trans

96%

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About This Item

Empirische Formel (Hill-System):
C6H12O
CAS-Nummer:
1003-38-9
Molekulargewicht:
100.16
Beilstein:
102563
EG-Nummer:
213-707-6
MDL-Nummer:
MFCD00005369
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24893560
NACRES:
NA.22

Assay

96%

Form

liquid

Brechungsindex

n20/D 1.404 (lit.)

bp

90-92 °C (lit.)

Dichte

0.833 g/mL at 25 °C (lit.)

SMILES String

CC1CCC(C)O1

InChI

1S/C6H12O/c1-5-3-4-6(2)7-5/h5-6H,3-4H2,1-2H3

InChIKey

OXMIDRBAFOEOQT-UHFFFAOYSA-N

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Piktogramme

Flame
GHS02

Signalwort

Warning

H-Sätze

H226

Gefahreneinstufungen

Flam. Liq. 3

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

80.6 °F - closed cup

Flammpunkt (°C)

27 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Tetrahydropyran anhydrous, 99%

Sigma-Aldrich

293105

Tetrahydropyran

Cyclopentylmethylether inhibitor-free, anhydrous, ≥99.9%

Sigma-Aldrich

791962

Cyclopentylmethylether

Tetrahydropyran-2-methanol 98%

Sigma-Aldrich

T14605

Tetrahydropyran-2-methanol

3,4-Bis(hydroxymethyl)furan 98%

Sigma-Aldrich

738247

3,4-Bis(hydroxymethyl)furan

Matthew R Grochowski et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(39), 12363-12371 (2012-08-24)
Carbohydrates, such as fructose, can be fully dehydroxylated to 2,5-dimethyltetrahydrofuran (DMTHF), a valuable chemical and potential gasoline substitute, by the use of a dual catalytic system consisting of HI and RhX(3) (X=Cl, I). A mechanistic study has been carried out
M S Akhlaq et al.
International journal of radiation biology and related studies in physics, chemistry, and medicine, 51(1), 91-102 (1987-01-01)
Thiyl radicals (RS) formed by the reaction of radiolytically generated OH radicals with thiols, e.g. 1,4-dithiothreitol (DTT), react with cis- and trans-2,5-dimethyltetrahydrofuran by abstracting an H atom in the alpha-position to the ether function (k approximately equal to 5 X
Weiran Yang et al.
ChemSusChem, 3(5), 597-603 (2010-05-04)
Existing technologies to produce liquid fuels from biomass are typically energy-intensive, multistep processes. Many of these processes use edible biomass as starting material. Carbohydrates, such as mono- and polysaccharides and cellulose, typically constitute 50-80% of plant biomass. Herein, we report
A S Anderson et al.
The Journal of organic chemistry, 65(15), 4648-4654 (2000-08-26)
2'-Deoxy-5-methyleneuridin-5-yl (1) is produced in a variety of DNA damage processes and is believed to result in the formation of lesions that are mutagenic and refractory to enzymatic repair. 2'-Deoxy-5-methyleneuridin-5-yl (1) was independently generated under anaerobic conditions via Norrish Type
John M Simmie
The journal of physical chemistry. A, 116(18), 4528-4538 (2012-04-13)
The enthalpies of formation, entropies, specific heats at constant pressure, enthalpy functions, and all carbon-hydrogen and carbon-methyl bond dissociation energies have been computed using high-level methods for the cyclic ethers (oxolanes) tetrahydrofuran, 2-methyltetrahydrofuran, and 2,5-dimethyltetrahydrofuran. Barrier heights for hydrogen-abstraction reactions
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