ALD00230

Sodium 4,4-difluorocyclohexanesulfinate

• Synonym(e): Baran DFHS-Na Reagent
• Empirische Formel (Hill-System): C₆H₉F₂NaO₂S
• CAS-Nummer: 1622013-58-4
• Molekulargewicht: 206.19
• MDL-Nummer: MFCD28124334
• UNSPSC-Code: 12352101
• PubChem Substanz-ID: 329772643
• NACRES: NA.22

Eigenschaften

• Form: powder
• Qualitätsniveau: 100
• Eignung der Reaktion: reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation
• mp (Schmelzpunkt): 290-295 °C
• SMILES String: O=S(C1CCC(F)(F)CC1)[O-].[Na+]
• InChI: 1S/C6H10F2O2S.Na/c7-6(8)3-1-5(2-4-6)11(9)10;/h5H,1-4H2,(H,9,10);/q;+1/p-1
• InChIKey: YVVCXFAMBAWLEV-UHFFFAOYSA-M

Beschreibung

Anwendung

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Sonstige Hinweise

Radical-Based Regioselective C-H Functionalization of Electron-Deficient Heteroarenes: Scope, Tunability, and Predictability

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable