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ALD00106

Sigma-Aldrich

5-Methoxycarbonyl-1,2,3-triazine

Synonym(e):

1,2,3-Triazine-5-carboxylic acid, methyl ester

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About This Item

Empirische Formel (Hill-System):
C5H5N3O2
CAS-Nummer:
150017-40-6
Molekulargewicht:
139.11
MDL-Nummer:
MFCD13195446
UNSPSC-Code:
12352100
PubChem Substanz-ID:
329772591
NACRES:
NA.22

Form

powder

Lagertemp.

−20°C

SMILES String

O=C(OC)C1=CN=NN=C1

InChI

1S/C5H5N3O2/c1-10-5(9)4-2-6-8-7-3-4/h2-3H,1H3

InChIKey

DZONTPIFZFRSGP-UHFFFAOYSA-N

Anwendung

1,2,3-Triazines have been shown to be reactive substrates in inverse electron demand Diels-Alder strategies. Recent examples by the Boger Research Group have utilized this reactive motif in the construction of highly functionalized N-containing heterocycles.

Sonstige Hinweise

Inverse Electron Demand Diels–Alder Reactions of 1, 2, 3-Triazines: Pronounced Substituent Effects on Reactivity and Cycloaddition Scope
Total Syntheses of (-)-Pyrimidoblamic Acid and P-3A

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Artikel

Inverse Electron Demand Diels–Alder Reactions of 1,2,4,5-Tetrazines and 1,2,3-Triazines

The inverse electron demand Diels-Alder reactions of electron-deficient heterocycles are significant cycloaddition reactions for the total synthesis of natural products containing highly substituted and functionalized heteroaromatic ring systems.

Verwandter Inhalt

Boger Group – Professor Product Portal

As the exploration of the properties of complex natural products becomes increasingly more sophisticated with the technological advances being made in their screening and evaluation and as structural details of their interaction with biological targets becomes more accessible, the importance and opportunities for providing unique solutions to complex biological problems has grown. The Boger Lab addresses these challenging problems by understanding the complex solutions and subtle design elements that nature has provided in the form of a natural product and work to extend the solution through rational design elements to provide more selective, more efficacious, or more potent agents designed specifically for the problem or target under investigation. The resulting efforts have reduced many difficult or intractable synthetic challenges to manageable problems providing an approach not only to the natural product but one capable of simple extrapolation to a series of structural analogs with improved selectivity and efficacy.

Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..

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