930059

S-Phenyl methanethioate

• Synonym(e): Phenyl thioCORMate, Phenyl thioformate
• Empirische Formel (Hill-System): C₇H₆OS
• CAS-Nummer: 27064-03-5
• Molekulargewicht: 138.19
• MDL-Nummer: MFCD32756471
• UNSPSC-Code: 12352101
• NACRES: NA.06

Eigenschaften

• Form: liquid
• Qualitätsniveau: 100
• Brechungsindex: n/D 1.586
• Dichte: 1.134 g/mL
• Funktionelle Gruppe: thioether
• Lagertemp.: −20°C
• SMILES String: [H]C(SC1=CC=CC=C1)=O
• InChI: 1S/C7H6OS/c8-6-9-7-4-2-1-3-5-7/h1-6H
• InChIKey: ITJOOMDVHPTIRB-UHFFFAOYSA-N

Beschreibung

Anwendung

S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO₂ phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 221.0 °F
• Flammpunkt (°C): 105 °C