677922

[Bis(trifluormethansulfonyl)imidat](triphenylphosphin)gold(I) (2:1) Toluol-Addukt

• Synonym(e): [Bis-(trifluormethansulfonyl)-imidat](PPh₃)-gold(I) (2:1) Toluoladdukt
• Lineare Formel: (C₂₀H₁₅AuF₆NO₄PS₂) 2 · C₇H₈
• Molekulargewicht: 1570.93
• MDL-Nummer: MFCD09038445
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24885406
• NACRES: NA.22

Eigenschaften

• Form: solid
• Eignung der Reaktion: core: gold; reagent type: catalyst
• SMILES String: [Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
• InChI: 1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h2*1-15H;2-6H,1H3;;;;/q;;;2*-1;2*+1
• InChIKey: SIVCTOVPPFSWEF-UHFFFAOYSA-N

Beschreibung

Anwendung

Gold Catalysts — 21st Century ′Gold Rush′

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct can be used as a catalyst in the 1,3-isomerisation of propargylic alcohols to enones via Meyer-Schuster rearrangement.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable