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Merck

556696

Sigma-Aldrich

N,N′-Di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamin

sublimed grade, 99%

Synonym(e):

N,N′-Bis-(naphthalin-1-yl)-N,N′-bis-(phenyl)-benzidin, NPB, NPD

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About This Item

Empirische Formel (Hill-System):
C44H32N2
CAS-Nummer:
Molekulargewicht:
588.74
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

Qualität

sublimed grade

Assay

99%

Verlust

0.5 wt. % loss on heating, 345°C (typical, TGA)

mp (Schmelzpunkt)

279-283 °C (lit.)

Energie der Orbitale

HOMO 5.5 eV 
LUMO 2.4 eV 

Leistung von OLED-Bauelementen

ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al

  • Color: red
  • Max. Luminance: 24529 Cd/m2
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V

ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: green
  • Max. Luminance: 207839 Cd/m2
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V

ITO/NPD/mCP/BCPO:FIrpic (8%)/TAZ/LiF/Al
  • Color: blue
  • Max. Luminance: 35677 Cd/m2
  • Max. EQE: 23.5 %
  • Turn-On Voltage: 2.8 V

ITO/PEDOT:PSS/NPD/TCTA/m-CBTZ:Ir(Bt)2(acac) (10%)/TPBI/LiF/Al
  • Color: yellow
  • Max. Luminance: 106000 Cd/m2
  • Max. EQE: 17.5 %
  • Turn-On Voltage: 3 V

SMILES String

c1ccc(cc1)N(c2ccc(cc2)-c3ccc(cc3)N(c4ccccc4)c5cccc6ccccc56)c7cccc8ccccc78

InChI

1S/C44H32N2/c1-3-17-37(18-4-1)45(43-23-11-15-35-13-7-9-21-41(35)43)39-29-25-33(26-30-39)34-27-31-40(32-28-34)46(38-19-5-2-6-20-38)44-24-12-16-36-14-8-10-22-42(36)44/h1-32H

InChIKey

IBHBKWKFFTZAHE-UHFFFAOYSA-N

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Allgemeine Beschreibung

TGA/DSC Lot specific traces available upon request

Anwendung

Hole transporting material for OLED devices

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)


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Tsuzuki, T.; Tokito, S.
Applied Physics Letters, 94, 033302-033302 (2009)
Phenylcarbazole-dipyridyl triazole hybrid as bipolar host material for phosphorescent OLEDs
Hung, W.; et al.
Journal of Materials Chemistry, 22, 5410-5418 (2012)
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Environmental science and pollution research international, 22(9), 7176-7182 (2014-12-17)
The aims of this study were to provide basic data for determining policies on air quality for multi-user facilities, including the legal enrollment of the indoor air quality regulation as designated by the Ministry of Environment, and to establish control

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