541508

2-Chlor-5,5-dimethyl-1,3,2-dioxaphosphorinan-2-oxid

95%

• Synonym(e): 2,2-Dimethyltrimethylene phosphorochloridate, 2-Chloro-2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinane, 2-Chloro-5,5-dimethyl-1,3,2λ5-dioxaphosphinan-2-one, 2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide, 2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinan-2-one, 2-Chloro-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane, 2-Chloro-5,5-dimethyl-2-oxodioxaphosphorinane, 5,5-Dimethyl-2-chloro-2-oxo-1,3,2-dioxaphosphorinane
• Empirische Formel (Hill-System): C₅H₁₀ClO₃P
• CAS-Nummer: 4090-55-5
• Molekulargewicht: 184.56
• EG-Nummer: 223-831-2
• MDL-Nummer: MFCD03425416
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24878541
• NACRES: NA.22

Eigenschaften

• Assay: 95%
• mp (Schmelzpunkt): 97-102 °C (lit.)
• SMILES String: CC1(C)COP(Cl)(=O)OC1
• InChI: 1S/C5H10ClO3P/c1-5(2)3-8-10(6,7)9-4-5/h3-4H2,1-2H3
• InChIKey: VZMUCIBBVMLEKC-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane 2-oxide is also referred to as 5,5-dimethyl-2-oxo-2-chloro-1,3,2-dioxaphosphinane (DMOCP). It can be prepared by reacting phosphorous oxychloride (in dry toluene) with 2,2-dimethyl-1,3-propane diol and triethyl amine.

Anwendung

2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane 2-oxide may be used in the synthesis of 5,5-dimethyl-2-oxido-[1,3,2]-dioxaphosphorinane-2-yl-amino carboxylates and cyclic diguanosine monophosphate (c-di-GMP).

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges