416428

2,2′-Methylen-bis[(4S)-4-phenyl-2-oxazolin]

97%

• Synonym(e): (S,S)-2,2′-Methylenbis-(4-phenyl-2-oxazolin)
• Empirische Formel (Hill-System): C₁₉H₁₈N₂O₂
• CAS-Nummer: 132098-59-0
• Molekulargewicht: 306.36
• Beilstein: 4202633
• MDL-Nummer: MFCD00192295
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24866074
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: viscous liquid
• Optische Aktivität: [α]20/D ~−90°, c = 1 in ethanol
• Brechungsindex: n20/D 1.586 (lit.)
• bp: 131-134 °C/0.01 mmHg (lit.)
• Dichte: 1.28 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: ether; phenyl
• SMILES String: C1OC(CC2=N[C@H](CO2)c3ccccc3)=N[C@H]1c4ccccc4
• InChI: 1S/C19H18N2O2/c1-3-7-14(8-4-1)16-12-22-18(20-16)11-19-21-17(13-23-19)15-9-5-2-6-10-15/h1-10,16-17H,11-13H2/t16-,17-/m1/s1
• InChIKey: IUFHJPXOLHSJTC-IAGOWNOFSA-N

Beschreibung

Anwendung

C₂ symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 230.0 °F - closed cup
• Flammpunkt (°C): 110 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter