393290

Tris-(dimethylamido)-phosphin

97%

• Synonym(e): HMPT, Hexamethyl-phosphorigsäure-triamid
• Lineare Formel: P[N(CH₃)₂]₃
• CAS-Nummer: 1608-26-0
• Molekulargewicht: 163.20
• Beilstein: 906778
• MDL-Nummer: MFCD00008301
• UNSPSC-Code: 12161700
• PubChem Substanz-ID: 24864511
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: liquid
• Eignung der Reaktion: reagent type: ligand; reaction type: Reductions; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Wittig Reaction
• Brechungsindex: n20/D 1.463 (lit.)
• bp: 48-50 °C/12 mmHg (lit.)
• Dichte: 0.898 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: phosphine
• SMILES String: CN(C)P(N(C)C)N(C)C
• InChI: 1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
• InChIKey: XVDBWWRIXBMVJV-UHFFFAOYSA-N

Beschreibung

Anwendung

Tris(dimethylamino)phosphine can be used a reagent in combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; for hydroxyl group activation; dehydrations.

Tris(dimethylamino)phosphine can be used as a:

• Ligand in the preparation of arene-ruthenium(II) complex which is used as a catalyst in hydration of nitriles to amides.
• Phosphorus source along with InCl₃ in the synthesis of InP colloidal quantum dots (QDs).
• Deoxygenating agent for some α-dicarbonyl compounds in the presence of fullerene C₆₀.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07
• Signalwort: Danger
• H-Sätze: H226,H315,H319,H340,H350
• P-Sätze: P202 - P210 - P233 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Skin Irrit. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 80.6 °F - closed cup
• Flammpunkt (°C): 27 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter