337498

(1,5-Cyclooctadien)(pyridin)(tricyclohexylphosphin)-iridium(I)-hexafluorphosphat

85%

• Synonym(e): (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF₆, Crabtree’s catalyst, Iridium(I)-hexafluorophosphat (1,5-Cyclooctadien)-(pyridin)-(tricyclohexylphosphin)-Komplex
• Empirische Formel (Hill-System): C₃₁H₅₀F₆IrNP₂
• CAS-Nummer: 64536-78-3
• Molekulargewicht: 804.89
• MDL-Nummer: MFCD00075097
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24860483
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 85%
• Eignung der Reaktion: core: iridium; reagent type: catalyst
• mp (Schmelzpunkt): 175 °C (dec.) (lit.)
• SMILES String: [Ir+].c1ccncc1.F[P-](F)(F)(F)(F)F.C2CC=CCCC=C2.C3CCC(CC3)P(C4CCCCC4)C5CCCCC5
• InChI: 1S/C18H33P.C8H12.C5H5N.F6P.Ir/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;1-2-4-6-5-3-1;1-7(2,3,4,5)6;/h16-18H,1-15H2;1-2,7-8H,3-6H2;1-5H;;/q;;;-1;+1/b;2-1-,8-7-;;;
• InChIKey: UJXHUUQZACSUOG-KJWGIZLLSA-N

Beschreibung

Anwendung

Homogeneous hydrogenation catalyst hydroboration catalyst.

Catalyst for alkene hydrogenation, isomerization, and hydroboration; also for hydrogen isotope exchange reaction.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves