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Merck

290890

Sigma-Aldrich

Dibutylzinndiacetat

technical grade

Synonym(e):

Diacetoxydibutylzinn

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About This Item

Lineare Formel:
(CH3CH2CH2CH2)2Sn(OCOCH3)2
CAS-Nummer:
Molekulargewicht:
351.03
Beilstein:
4136035
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22

Qualität

technical grade

Qualitätsniveau

Dampfdichte

12 (vs air)

Dampfdruck

1.3 mmHg ( 25 °C)

Brechungsindex

n20/D 1.471 (lit.)

bp

142-145 °C/10 mmHg (lit.)

mp (Schmelzpunkt)

7-10 °C (lit.)

Dichte

1.32 g/mL at 25 °C (lit.)

SMILES String

CCCC[Sn](CCCC)(OC(C)=O)OC(C)=O

InChI

1S/2C4H9.2C2H4O2.Sn/c2*1-3-4-2;2*1-2(3)4;/h2*1,3-4H2,2H3;2*1H3,(H,3,4);/q;;;;+2/p-2

InChIKey

JJLKTTCRRLHVGL-UHFFFAOYSA-L

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Allgemeine Beschreibung

Dibutyltin diacetate is an organotin compound that is commonly used as a catalyst in organic synthesis.

Anwendung

Dibutyltin diacetate can be used as a catalyst to synthesize:
  • Wittenberger tetrazole derivatives by reacting with various nitriles in the presence of trimethylsilyl azide.
  • Carbamate derivatives from various isocyanates and alcohols in the presence of dichloromethane as solvent.
  • Urea derivatives from aryl isocyanates and various amines in the presence of 4-methylmorpholine.

Signalwort

Danger

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 - STOT SE 1 Oral

Zielorgane

thymus gland, thymus gland,Immune system

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

302.9 °F - Pensky-Martens closed cup

Flammpunkt (°C)

150.5 °C - Pensky-Martens closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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B B Harsanyi et al.
Journal of dental research, 70(6), 991-996 (1991-06-01)
The hamster cheek pouch provides a suitable model system for the mucous-membrane irritation testing of dental materials. Poor retention of materials or difficulties in histopathological interpretation caused by surgical artifacts have been reported in published techniques. We describe a new
Critical gestational day of teratogenesis by di-n-butyltin diacetate in rats.
T Noda et al.
Bulletin of environmental contamination and toxicology, 49(5), 715-722 (1992-11-01)
T Noda et al.
Toxicology, 167(3), 181-189 (2001-10-02)
The present study was designed to assess changes in the teratogenic potency of di-n-butyltin diacetate (DBTA) with increasing maternal age in rats. Pregnant Wistar rats of 3, 7.5 or 12 months were treated orally with DBTA at 0, 7.5, 10
T Noda et al.
Archives of environmental contamination and toxicology, 23(2), 216-222 (1992-08-01)
Teratological tests were conducted on di-n-butyltin diacetate (DBTA), and n-butyltin trichloride (MBTC). Pregnant Wistar rats were treated orally with DBTA at doses of 0, 1.7, 5.0, 10.0, and 15.0 mg/kg/day or with MBTC at doses of 0, 50, 100, 200
Yun-Chae Jung et al.
Scientific reports, 7(1), 17482-17482 (2017-12-14)
Amorphous poly(ethylene ether carbonate) (PEEC), which is a copolymer of ethylene oxide and ethylene carbonate, was synthesized by ring-opening polymerization of ethylene carbonate. This route overcame the common issue of low conductivity of poly(ethylene oxide)(PEO)-based solid polymer electrolytes at low

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